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Nongeminate recombination in organic bulk heterojunction solar cells: Contribution of exciton–polaron interaction

Abstract

A new model to explain nongeminate recombination in organic bulk heterojunction solar cells is presented. We suggest that the annihilation of excitons on charge carriers at the interface between donor and acceptor phases competes with the bimolecular recombination of Coulombically bound electron–hole pairs. The exciton–polaron interaction gives visible contribution to the reduction of Langevin recombination. An analytical formula, which describes the reduction prefactor, has been derived. We demonstrate that exciton–charge carrier interactions cause an increase of the recombination order.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
Physica Status Solidi-Rapid Research Letters no. 6, edition 7, pages 300 - 302,
ISSN: 1862-6254
Language:
English
Publication year:
2012
Bibliographic description:
Szmytkowski J.: Nongeminate recombination in organic bulk heterojunction solar cells: Contribution of exciton–polaron interaction// Physica Status Solidi-Rapid Research Letters. -Vol. 6, iss. 7 (2012), s.300-302
Verified by:
Gdańsk University of Technology

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