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Abstract
The reactions of R2P-P(SiMe3)Li (R = tBu, iPr2N) with [Cp2MoCl2] yield terminal phosphanylphosphido complexes formally via the insertion of the phosphinidene P-atom into the C - H bond of a cyclopentadienyl ring and the migration of the hydrogen atom or SiMe3 moiety to the molybdenum centre. Solid state structures of [Cp(C5H4P-PtBu2)MoH], [Cp(C5H4P-PtBu2)Mo(SiMe3)] and [Cp{C5H4P-P(NiPr2)2}Mo(SiMe3)] were established by single crystal X-ray diffraction. The proposed reaction path is supported by the results of NMR studies and DFT calculations.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
POLYHEDRON
no. 39,
ISSN: 0277-5387 - Language:
- English
- Publication year:
- 2012
- Bibliographic description:
- Kruczyński T., Grubba R., Kazimierczuk K., Pikies J.: Syntheses and structures of the first terminal phosphanylphosphido complexes of molybdenum(IV)// POLYHEDRON. -Vol. 39, nr. iss. 1 (2012),
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.poly.2012.03.023
- Verified by:
- Gdańsk University of Technology
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