Abstract
The results of electrical conductivity studies, structural measurements and thermogravimetric analysis of La1−xTbxNbO4+δ (x = 0.00, 0.05, 0.1, 0.15, 0.2, 0.3) are presented and discussed. The phase transition temperatures, measured by high-temperature x-ray diffraction, were 480 °C, 500 °C, and 530 °C for La0.9Tb0.1NbO4+δ, La0.8Tb0.2NbO4+δ, and La0.7Tb0.3NbO4+δ, respectively. The impedance spectroscopy results suggest mixed conductivity of oxygen ions and electron holes in dry conditions and protons in wet. The water uptake has been analyzed by the means of thermogravimetry revealing a small mass increase in the order of 0.002% upon hydration, which is similar to the one achieved for undoped lanthanum orthoniobate.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
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Crystals
no. 9,
edition 2,
pages 1 - 14,
ISSN: 2073-4352 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Dzierzgowski K., Wachowski S. L., Gazda M., Mielewczyk-Gryń A. D.: Terbium Substituted Lanthanum Orthoniobate: Electrical and Structural Properties// Crystals. -Vol. 9, iss. 2 (2019), s.1-14
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/cryst9020091
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- Molenda, J.; Kupecki, J.; Baron, R.; Blesznowski, M.; Brus, G.; Brylewski, T.; Bucko, M.; Chmielowiec, J.; Cwieka, K.; Gazda, M.; et al. Status report on high temperature fuel cells in Poland-Recent advances and achievements. Int. J. Hydrogen Energy 2017, 42, 4366-4403. [CrossRef] open in new tab
- Gdula-Kasica, K.; Mielewczyk-Gryn, A.; Molin, S.; Jasinski, P.; Krupa, A.; Kusz, B.; Gazda, M. Optimization of microstructure and properties of acceptor-doped barium cerate. Solid State Ionics 2012, 225, 245-249. [CrossRef] open in new tab
- Haugsrud, R.; Norby, T. Proton conduction in rare-earth ortho-niobates and ortho-tantalates. Nat. Mater. 2006, 5, 193-196. [CrossRef] open in new tab
- Animitsa, I.; Iakovleva, A.; Belova, K. Electrical properties and water incorporation in A-site deficient perovskite La 1-x Ba x Nb 3 O 9-0.5x . J. Solid State Chem. 2016, 238, 156-161. [CrossRef] open in new tab
- Hibino, T.; Mizutani, K.; Yajima, T.; Iwahara, H. Evaluation of proton conductivity in SrCeO 3 , BaCeO 3 , CaZrO 3 and SrZrO 3 by temperature programmed desorption method. Solid State Ionics 1992, 57, 303-306. [CrossRef] open in new tab
- Escolástico, S.; Vert, V.B.; Serra, J.M. Preparation and characterization of nanocrystalline mixed proton-electronic conducting materials based on the system Ln 6 WO 12 . Chem. Mater. 2009, 21, 3079-3089. [CrossRef] open in new tab
- Yajima, T.; Kazeoka, H.; Yogo, T.; Iwahara, H. Proton conduction in sintered oxides based on CaZrO 3 . Solid State Ionics 1991, 47, 271-275. [CrossRef] open in new tab
- Sakai, T.; Isa, K.; Matsuka, M.; Kozai, T.; Okuyama, Y.; Ishihara, T.; Matsumoto, H. Electrochemical hydrogen pumps using Ba doped LaYbO 3 type proton conducting electrolyte. Int. J. Hydrogen Energy 2013, 38, 6842-6847. [CrossRef] open in new tab
- Haugsrud, R.; Ballesteros, B.; Lira-Cantu, M.; Norby, T. Ionic and electronic conductivity of 5% Ca-doped GdNbO 4 . J. Electrochem. Soc. 2006, 153, J87-J90. [CrossRef] open in new tab
- Bayliss, R.D.; Pramana, S.S.; An, T.; Wei, F.; Kloc, C.L.; White, A.J.P.; Skinner, S.J.; White, T.J.; Baikie, T. Fergusonite-type CeNbO 4+δ : Single crystal growth, symmetry revision and conductivity. J. Solid State Chem. 2013, 204, 291-297. [CrossRef] open in new tab
- Li, C.; Bayliss, R.D.; Skinner, S.J. Crystal structure and potential interstitial oxide ion conductivity of LnNbO 4 and LnNb 0.92 W 0.08 O 4.04 (Ln = La, Pr, Nd). Solid State Ionics 2014, 262, 530-535. [CrossRef] open in new tab
- Huang, H.; Wang, T.; Zhou, H.; Huang, D.; Wu, Y.; Zhou, G.; Hu, J.; Zhan, J. Luminescence, energy transfer, and up-conversion mechanisms of Yb3+and Tb3+co-doped LaNbO 4 . J. Alloys Compd. 2017, 702, 209-215. [CrossRef] open in new tab
- Haugsrud, R.; Norby, T. High-temperature proton conductivity in acceptor-doped LaNbO 4 . Solid State Ionics 2006, 177, 1129-1135. [CrossRef] open in new tab
- Hakimova, L.; Kasyanova, A.; Farlenkov, A.; Lyagaeva, J.; Medvedev, D.; Demin, A.; Tsiakaras, P. Effect of isovalent substitution of La 3+ in Ca-doped LaNbO 4 on the thermal and electrical properties. Ceram. Int. 2019, 45, 209-215. [CrossRef] open in new tab
- Mielewczyk-Gryn, A.; Wachowski, S.; Zagórski, K.; Jasiński, P.; Gazda, M. Characterization of magnesium doped lanthanum orthoniobate synthesized by molten salt route. Ceram. Int. 2015, 41, 7847-7852. [CrossRef] open in new tab
- Mielewczyk-Gryn, A.; Gdula, K.; Lendze, T.; Kusz, B.; Gazda, M. Nano-and microcrystals of doped niobates. Cryst. Res. Technol. 2010, 45, 1225-1228. [CrossRef] open in new tab
- Fjeld, H.; Kepaptsoglou, D.M.; Haugsrud, R.; Norby, T. Charge carriers in grain boundaries of 0.5% Sr-doped LaNbO 4 . Solid State Ionics 2010, 181, 104-109. [CrossRef] open in new tab
- Mokkelbost, T.; Lein, H.L.; Vullum, P.E.; Holmestad, R.; Grande, T.; Einarsrud, M.-A. Thermal and mechanical properties of LaNbO 4 -based ceramics. Ceram. Int. 2009, 35, 2877-2883. [CrossRef] open in new tab
- Nguyen, D.; Kim, Y.H.; Lee, J.S.; Fisher, J.G. Structure, morphology, and electrical properties of proton conducting La 0.99 Sr 0.01 NbO 4-δ synthesized by a modified solid state reaction method. Mater. Chem. Phys. 2017, 202, 320-328. [CrossRef] open in new tab
- Brandão, A.D.; Antunes, I.; Frade, J.R.; Torre, J.; Kharton, V.V.; Fagg, D.P. Enhanced Low-Temperature Proton Conduction in Sr 0.02 La 0.98 NbO 4−δ by Scheelite Phase Retention. Chem. Mater. 2010, 22, 6673-6683. [CrossRef] open in new tab
- Wachowski, S.; Mielewczyk-Gryn, A.; Gazda, M. Effect of isovalent substitution on microstructure and phase transition of LaNb 1−x M x O 4 (M = Sb, V or ta; x = 0.05 to 0.3). J. Solid State Chem. 2014, 219, 201-209. [CrossRef] open in new tab
- Brandão, A.D.; Nasani, N.; Yaremchenko, A.A.; Kovalevsky, A.V.; Fagg, D.P. Solid solution limits and electrical properties of scheelite SryLa 1-y Nb 1-x V x O 4-δ materials for x = 0.25 and 0.30 as potential proton conducting ceramic electrolytes. Int. J. Hydrogen Energy 2018, 43, 18682-18690. [CrossRef] open in new tab
- Wachowski, S.; Mielewczyk-Gryn, A.; Zagorski, K.; Li, C.; Jasinski, P.; Skinner, S.J.; Haugsrud, R.; Gazda, M. Influence of Sb-substitution on ionic transport in lanthanum orthoniobates. J. Mater. Chem. A 2016, 4, 11696-11707. [CrossRef] open in new tab
- Mielewczyk-Gryn, A.; Wachowski, S.; Strychalska, J.; Zagórski, K.; Klimczuk, T.; Navrotsky, A.; Gazda, M. Heat capacities and thermodynamic properties of antimony substituted lanthanum orthoniobates. Ceram. Int. 2016, 42, 7054-7059. [CrossRef] open in new tab
- Mielewczyk-Gryn, A.; Wachowski, S.; Lilova, K.I.; Guo, X.; Gazda, M.; Navrotsky, A. Influence of antimony substitution on spontaneous strain and thermodynamic stability of lanthanum orthoniobate. Ceram. Int. 2015, 41, 2128-2133. [CrossRef] open in new tab
- Wachowski, S.; Kamecki, B.; Winiarz, P.; Dzierzgowski, K.; Mielewczyk-Gryń, A.; Gazda, M. Tailoring structural properties of lanthanum orthoniobates through an isovalent substitution on the Nb-site. Inorg. Chem. Front. 2018, 5, 2157-2166. [CrossRef] open in new tab
- Li, M.; Wu, R.; Zhu, L.; Cheng, J.; Hong, T.; Xu, C. Enhanced sinterability and conductivity of cobalt doped lanthanum niobate as electrolyte for proton-conducting solid oxide fuel cell. Ceram. Int. 2019, 45, 573-578. [CrossRef] open in new tab
- Dzierzgowski, K.; Wachowski, S.; Gojtowska, W.; Lewandowska, I.; Jasiński, P.; Gazda, M.; Mielewczyk-Gryń, A. Praseodymium substituted lanthanum orthoniobate: Electrical and structural properties. Ceram. Int. 2018, 44, 8210-8215. [CrossRef] open in new tab
- Packer, R.J.; Skinner, S.J.; Yaremchenko, A.A.; Tsipis, E.V.; Kharton, V.V.; Patrakeev, M.V.; Bakhteeva, Y.A. Lanthanum substituted CeNbO 4+δ scheelites: Mixed conductivity and structure at elevated temperatures. J. Mater. Chem. 2006, 16, 3503. [CrossRef] open in new tab
- Rodríguez-Carvajal, J. Recent Developments for the Program FULLPROF; Commission on Powder Diffraction: Perth, Australia, 2001; Volume 26, ISBN 4971168915. open in new tab
- Shannon, R.D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. Sect. A 1976, 32, 751-767. [CrossRef] open in new tab
- Stubičan, V.S. High-Temperature Transitions in Rare Earth Niobates and TantaIates. J. Am. Ceram. Soc. 1964, 47, 55-58. [CrossRef] open in new tab
- Yamazaki, Y.; Babilo, P.; Haile, S.M. Defect chemistry of yttrium-doped barium zirconate: A thermodynamic analysis of water uptake. Chem. Mater. 2008, 20, 6352-6357. [CrossRef] open in new tab
- Mielewczyk-Gryń, A. Water uptake analysis of the acceptor-doped lanthanum orthoniobates. J. Therm. Anal. Calorim. 2019, submitted. open in new tab
- Huse, M.; Norby, T.; Haugsrud, R. Effects of A and B site acceptor doping on hydration and proton mobility of LaNbO 4 . Int. J. Hydrogen Energy 2012, 37, 8004-8016. [CrossRef] open in new tab
- Abrantes, J.C.C.; Labrincha, J.A.; Frade, J.R. Applicability of the brick layer model to describe the grain boundary properties of strontium titanate ceramics. J. Eur. Ceram. Soc. 2000, 20, 1603-1609. [CrossRef] open in new tab
- Haile, S.M.; West, D.L.; Campbell, J. The role of microstructure and processing on the proton conducting properties of gadolinium-doped barium cerate. J. Mater. Res. 1998, 13, 1576-1595. [CrossRef] open in new tab
- Berger, P.; Mauvy, F.; Grenier, J.-C.; Sata, N.; Magrasó, A.; Haugsrud, R.; Slater, P.R. Proton-Conducting Ceramics: From Fundamentals to Applied Research; open in new tab
- Marrony, M., Ed.; Pan Stanford Publishing: Singapore, 2016; Chapter 1; pp. 1-72. open in new tab
- Mather, G.C.; Fisher, C.A.J.; Islam, M.S. Defects, dopants, and protons in LaNbO 4 . Chem. Mater. 2010, 22, 5912-5917. [CrossRef] open in new tab
- Packer, R.J.; Tsipis, E.V.; Munnings, C.N.; Kharton, V.V.; Skinner, S.J.; Frade, J.R. Diffusion and conductivity properties of cerium niobate. Solid State Ionics 2006, 177, 2059-2064. [CrossRef] open in new tab
- Wang, D.Y.; Park, D.S.; Griffith, J.; Nowick, A.S. Oxygen-ion conductivity and defect interactions in yttria-doped ceria. Solid State Ionics 1981, 2, 95-105. [CrossRef] open in new tab
- Guo, X.; Waser, R. Electrical properties of the grain boundaries of oxygen ion conductors: Acceptor-doped zirconia and ceria. Prog. Mater. Sci. 2006, 51, 151-210. [CrossRef] open in new tab
- Kilner, J.A.; Brook, R.J. A study of oxygen ion conductivity in doped non-stoichiometric oxides. Solid State Ionics 1982, 6, 237-252. [CrossRef] open in new tab
- Norby, T.; Larring, Y. Concentration and transport of protons in oxides. Curr. Opin. Solid State Mater. Sci. 1997, 2, 593-599. [CrossRef] open in new tab
- Islam, M.S.; Davies, R.A.; Fisher, C.A.J.; Chadwick, A.V. Defects and protons in the CaZrO 3 perovskite and Ba 2 In 2 O 5 brownmillerite: Computer modelling and EXAFS studies. Solid State Ionics 2001, 145, 333-338. [CrossRef] open in new tab
- Toyoura, K.; Sakakibara, Y.; Yokoi, T.; Nakamura, A.; Matsunaga, K. Oxide-ion conduction: Via interstitials in scheelite-type LaNbO 4 : A first-principles study. J. Mater. Chem. A 2018, 6, 12004-12011. [CrossRef] open in new tab
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