Search
Abstract
Rubber technology experiences a new age by the use of biowaste or natural fillers. In this regard, taking properties of reinforcing agents from biowaste fillers remains as the challenging matter. Chicken eggshell (ES) biowaste has recently been introduced to substitute calcium carbonate (CaCO3) duo to its superior properties and low price. In this work, composites based on acrylonitrile butadiene rubber (NBR) reinforced with ES and CaCO3 microfillers at various loading levels were prepared and characterized. To improve the interactions between fillers and the NBR matrix, ES and CaCO3 were surface-functionalized using a terpolymer, namely poly(vinyl 2-pyrrolidone-co-maleic acid-co-acrylic acid). Fourier-transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) were used to characterize the modified fillers. The incorporation of the functionalized fillers resulted in a significant rise in the maximum torque according to the rheometric measurements. The Young’s modulus of the ES-based and CaCO3-based compounds showed a mild improvement over a wide range of filler contents. The elongation at break of the NBR composites, however, was dependent on the filler content. This work provides exciting opportunities for the design of novel and innovative coupling agents to be used in rubber applications.
Citations
-
3 4
CrossRef
-
0
Web of Science
-
4 0
Scopus
Authors (11)
-
Eshwaran Subramani Bhagavatheswaran
-
Amit Das
-
Hadi Rastin
-
Hoda Saeidi
-
Seyed Hassan Jafari
-
Henri Vahabi
-
Hossein Khonakdar
-
Maryam Jouyandeh
-
Payam Zarrintaj
-
Mohammad Saeb
Cite as
Full text
- Publication version
- Accepted or Published Version
- License
-
open in new tab
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
JOURNAL OF POLYMERS AND THE ENVIRONMENT
no. 27,
pages 2478 - 2489,
ISSN: 1566-2543 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Bhagavatheswaran E., Das A., Rastin H., Saeidi H., Jafari S., Vahabi H., Khonakdar H., Formela K., Jouyandeh M., Zarrintaj P., Saeb M.: The Taste of Waste: The Edge of Eggshell Over Calcium Carbonate in Acrylonitrile Butadiene Rubber// JOURNAL OF POLYMERS AND THE ENVIRONMENT -Vol. 27, (2019), s.2478-2489
- DOI:
- Digital Object Identifier (open in new tab) 10.1007/s10924-019-01530-y
- Verified by:
- Gdańsk University of Technology
seen 128 times
Recommended for you
Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels
- M. Saeb,
- M. Ghaffari,
- H. Rastin
- + 8 authors