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Valence and ionic lowest-lying electronic states of ethyl formate as studied by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy, and ab initio calculations
Abstract
The highest resolution vacuum ultraviolet photoabsorption spectrum of ethyl formate, C2H5OCHO, yet reported is presented over the wavelength range 115.0–275.5 nm (10.75–4.5 eV) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series, observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of the vertical excitation energies and oscillator strengths. Calculations have also been carried out to determine the ionization energies and fine structure of the lowest ionic state of ethyl formate and are compared with a newly recorded He(I) photoelectron spectrum (from 10.1 to 16.1 eV). New vibrational structure is observed in the first photoelectron band. The photoabsorption cross sections have been used to calculate the photolysis lifetime of ethyl formate in the upper stratosphere (20–50 km).
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Authors (10)
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Marie-Jeanne Hubin-Franskin
- Universite de Liege Institut de Chimie Bat.
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Jacques Delwiche
- Universite de Liege Institut de Chimie Bat.
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Denis Duflot
- Universite Lille Sciences et Technologies Laboratorie de Physical Sciences
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N.j. Mason
- The Open University Dep. of Physical Sciences
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Soren Vrønning-Hoffmann
- Aarhus University Dep. of Physics
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N. C. Jones
- Aarhus University Dep. of Physics
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P. Limao-Vieira
- Universidade Nova Lisboa Departamento de Fisica
Cite as
Full text
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1063/1.4894762
- License
- Copyright (2014 AIP Publishing LLC)
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
JOURNAL OF CHEMICAL PHYSICS
no. 141,
pages 1 - 10,
ISSN: 0021-9606 - Language:
- English
- Publication year:
- 2014
- Bibliographic description:
- Śmiałek-Telega M., Łabuda M., Guthmuller J., Hubin-Franskin M., Delwiche J., Duflot D., Mason N., Vrønning-Hoffmann S., Jones N., Limao-Vieira P.: Valence and ionic lowest-lying electronic states of ethyl formate as studied by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy, and ab initio calculations// JOURNAL OF CHEMICAL PHYSICS. -Vol. 141, nr. 10 (2014), s.1-10
- DOI:
- Digital Object Identifier (open in new tab) 10.1063/1.4894762
- Verified by:
- Gdańsk University of Technology
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