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Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect

Abstract

Three dimensional chemically cross-linked polymer networks present a great challenge for recycling and reutilization of waste tire rubber. In this work, the covalently cross-linked networks of ground tire rubber (GTR) were degraded heterogeneously under 150 °C due to the synergistic effects of the soybean oil and controlled oxidation. The degradation mechanism was discussed using Horikx theory and Fourier transformation infrared spectroscopy (FTIR). The results showed that the structural evolution of sol and gel parts, which indicated that the sols consisted of degraded GTR chains with low molecular weight, while the gels were mainly composed of bound rubber coated carbon black, which are separated from the cross-linked network of GTR in a high degradation degree. The degraded GTR compound demonstrated an excellent reinforcing effect on solution styrene-butadiene rubber (SSBR), due to the presence of core-shell structured carbon black. This work provide an efficient and economic approach to degrade GTR and transform it into useful products.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
WASTE MANAGEMENT no. 78, pages 238 - 248,
ISSN: 0956-053X
Language:
English
Publication year:
2018
Bibliographic description:
Song P., Wan C., Xie Y., Formela K., Wang S.: Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect// WASTE MANAGEMENT. -Vol. 78, (2018), s.238-248
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.wasman.2018.05.054
Verified by:
Gdańsk University of Technology

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