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Volumes of N,N-dimethylacetamide solvated metal cations. Variation within the manganese(II) to zinc(II) series
Abstract
Densities and apparent molar volumes for Mn(ClO4)2,Co(ClO4)2 , Ni(ClO4)2,Cu(ClO4)2 , and Zn(ClO4)2 in N, N -dimethylacetamide (DMA) solutions at T = 298.15 K are reported. Densities and apparent molar volumes of tetrabutylammonium tetraphenylborate and tetrabutylammonium perchlorate were determined, and used to obtain the partial molar volume for the ClO4 − anion. The partial molar volumes of the DMA-solvated cations are derived, and their variation within the Mn2 + to Zn2 + series is discussed in terms of structure and stability of the coordination clusters. The ligand field effect on the partial molar volume is demonstrated.
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- Category:
- Magazine publication
- Type:
- Magazine publication
- Published in:
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JOURNAL OF CHEMICAL THERMODYNAMICS
no. 31,
ISSN: 0021-9614 - Publication year:
- 1999
- DOI:
- Digital Object Identifier (open in new tab) 10.1006/jcht.1999.0538
- Verified by:
- No verification
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