Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions

Anife Ahmedova; Sonya Zareva; Anna Dołęga

doi:10.1016/j.mencom.2020.07.039

Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions

Abstract

A template synthesis using 2-acetyl-1,3-indandione and ethylenediamine results in formation of octahedral Ni complex, whose crystal structure has been resolved using single crystal X-ray diffraction. The structure indicates that only exocyclic enolic oxygen atom of the triketone takes part in the condensation with ethylenediamine.

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Category:: Articles
Type:: artykuły w czasopismach
Published in:: MENDELEEV COMMUNICATIONS no. 30, pages 519 - 521,
ISSN: 0959-9436
Language:: English
Publication year:: 2020
Bibliographic description:: Ahmedova A., Zareva S., Dołęga A.: Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions// MENDELEEV COMMUNICATIONS -Vol. 30,iss. 4 (2020), s.519-521
DOI:: Digital Object Identifier (open in new tab) 10.1016/j.mencom.2020.07.039
Verified by:: Gdańsk University of Technology