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Optical rotation in the lithium triborate nonlinear crystal

Abstract

A dual-wavelength polarimetric technique at 633 and 661 nm has been used for the characterization of a nonlinear lithium triborate (LiB3O5) nonenantiomorphous biaxial crystal. The mismatch of the crystallographic and optical coordinate systems was taken into account. The optical rotatory power for light propagation along one of the optical axes is ρ = 7.06° mm−1. The gyration tensor component along the bisector between the x and y crystallographic axes has been measured as g12 = 4.31 × 10−5. Computed values based on the crystalline structure and electronic polarizabilities are in good agreement with those obtained experimentally.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
Journal of Applied Crystallography no. 56, pages 432 - 438,
ISSN: 1600-5767
Language:
English
Publication year:
2023
Bibliographic description:
Shopa M., Ftomyn N., Shopa Y.: Optical rotation in the lithium triborate nonlinear crystal// Journal of Applied Crystallography -,iss. 2 (2023), s.432-438
DOI:
Digital Object Identifier (open in new tab) 10.1107/s160057672300136x
Sources of funding:
  • Statutory activity/subsidy
Verified by:
Gdańsk University of Technology

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