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Abstract
The metal–metal bond in metal-rich chalcogenide is known to exhibit various structures and interesting physical properties. Ta2Se can be obtained by both arc-melting and solid-state pellet methods. Ta2Se crystallizes a layered tetragonal structure with space group P4/nmm (No. 129; Pearson symbol tP6). Each unit cell consists of four layers of body-centered close-packing Ta atoms sandwiched between two square nets of Se atoms, forming the Se–Ta–Ta–Ta–Ta–Se networks. Herein, we present magnetic susceptibility, resistivity, and heat capacity measurements on Ta2Se, which together indicate bulk superconductivity with Tc = 3.8(1) K. According to first-principles calculations, the d orbitals in Ta atoms dominate the Fermi level in Ta2Se. The flat bands at the Γ point in the Brillouin zone yield the van Hove singularities in the density of states around the Fermi level, which is intensified by introducing a spin–orbit coupling effect, and thus could be critical for the superconductivity in Ta2Se. The physical properties, especially superconductivity, are completely different from those of Ta-rich alloys or transition-metal dichalcogenide TaSe2.
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Authors (6)
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Xin Gui
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Qiang Chen
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Haidong Zhou
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Weiwei Xie
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
INORGANIC CHEMISTRY
no. 59,
pages 5798 - 5802,
ISSN: 0020-1669 - Language:
- English
- Publication year:
- 2020
- Bibliographic description:
- Gui X., Górnicka K., Chen Q., Zhou H., Klimczuk T., Xie W.: Superconductivity in Metal-Rich Chalcogenide Ta2Se// INORGANIC CHEMISTRY -Vol. 59,iss. 9 (2020), s.5798-5802
- DOI:
- Digital Object Identifier (open in new tab) 10.1021/acs.inorgchem.9b03656
- Verified by:
- Gdańsk University of Technology
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