Search results for: photorearrangement

• Do Phenyl Substituents Affect the Properties of Azobenzocrown Derivatives?

  Publication

  • E. Wagner-Wysiecka
  • P. Szulc
  • E. Luboch
  • J. Chojnacki
  • D. Laskowska
  • P. Miklaszewska
  • P. Sowiński

  - ChemPlusChem - Year 2023

  New products of photo- and thermal rearrangements of 19-membered azoxybenzocrown with phenyl substituents in benzene rings in the para positions to oligooxyethylene fragments are characterized. The yields of photochemical transformations depend on the solvent. Para-hydroxyazocrown is formed with yields over 50% in propan-2-ol. Ortho-hydroxyazobenzocrown is obtained with yields up to 70% in toluene/acetic acid mixture. Macrocyclic...

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