Search results for: cyanopyridines

• Gold(III) complexes with chloride and cyanopyridines: Facilitated hydrolysis of nitrile ligand to amide and antibacterial activity

  Publication

  • M. Ejnik
  • P. Bruździak
  • K. Gutmańska
  • A. Ciborska
  • M. Malik
  • D. Gudat
  • A. Brillowska-Dąbrowska
  • A. Dołęga

  - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY - Year 2025

  A range of novel simple gold(III) compounds has been synthesized in their monocrystalline form, including two previously unknown chloro-complexes of Au3+ with 2-cyanopyridine or 3-cyanopyridine, respectively. Our investigations have revealed the intricate nature of the reaction between 2-cyanopyridine and tetrachloroauric acid, yielding at least three distinct products. The main product, obtained in high yield, is a salt featuring...

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• Silver(I) complexes with nitrile ligands: New materials with versatile applications

  Publication

  • K. Gutmańska
  • P. Szweda
  • M. Daszkiewicz
  • T. Mazur
  • K. Szaciłowski
  • A. Ciborska
  • A. Dołęga

  - APPLIED ORGANOMETALLIC CHEMISTRY - Year 2023

  In the present study, the structure, thermal stability, conductive properties, and antimicrobial activity of silver(I) complexes with nitrile ligands were investigated. For the construction of the materials, 2-cyanopyridine (2-cpy), 4-cyanopyridine (4-cpy), 1,2-dicyanobenzene (1,2-dcb), and 1,3-dicyanobenzene (1,3-dcb) were used in addition to the silver nitrite and nitrate. Four new compounds were isolated and structurally characterized:...

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