Wiktoria Błaszkiewicz - Publications - Bridge of Knowledge

Wiktoria Błaszkiewicz

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Year 2025

The effect of substituents on the P–P and P=C bond properties in phosphanylphosphaalkenes
Publication
- A. Ziółkowska
- W. Błaszkiewicz
- T. Kruczyński
- DALTON TRANSACTIONS - Year 2025
A new lithium salt of diphosphane, (iPr₂N)PhP-P(SiMe₃)Li (2), featuring two electronically differentiated substituents, is presented. Its reaction with benzophenone was then carried out, yielding a novel phosphanylphosphaalkene (3). The isolated compound was subsequently treated with nBuLi and PhLi to obtain stable activators (3a and 3b) of the potential polymerization of phosphorus-rich compounds.

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