The effect of substituents on the P–P and P=C bond properties in phosphanylphosphaalkenes

Aleksandra Ziółkowska; Wiktoria Błaszkiewicz; Tomasz Kruczyński

doi:10.1039/d5dt00692a

The effect of substituents on the P–P and P=C bond properties in phosphanylphosphaalkenes

Abstract

A new lithium salt of diphosphane, (iPr₂N)PhP-P(SiMe₃)Li (2), featuring two electronically differentiated substituents, is presented. Its reaction with benzophenone was then carried out, yielding a novel phosphanylphosphaalkene (3). The isolated compound was subsequently treated with nBuLi and PhLi to obtain stable activators (3a and 3b) of the potential polymerization of phosphorus-rich compounds.

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Authors (3)

Aleksandra Ziółkowska dr inż.
Wiktoria Błaszkiewicz
Tomasz Kruczyński dr inż.
- Kennesaw State University

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Category:

Articles

Type:

artykuły w czasopismach dostępnych w wersji elektronicznej [także online]

Published in:

DALTON TRANSACTIONS pages 8041 - 8044,
ISSN: 1477-9226

Language:

English

Publication year:

2025

Bibliographic description:

Ziółkowska A., Błaszkiewicz W., Kruczyński T., The effect of substituents on the P–P and P=C bond properties in phosphanylphosphaalkenes, DALTON TRANSACTIONS,2025, iss. 54,10.1039/D5DT00692A

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