Emil Perzanowski - Publications - Bridge of Knowledge

Emil Perzanowski

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Year 2019

Structural and spectroscopic analysis of a new family of monomeric diphosphinoboranes
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- DALTON TRANSACTIONS - Year 2019
We present a series of amino- and aryl(diphosphino)boranes R2PB(R’’)PR’2, where R2P, R’2P = tBu2P, tBuPhP, Ph2P, Cy2P, and R’’ = iPr2N, Ph, which were obtained via the metathesis reaction of iPr2NBBr2 or PhBBr2 with selected lithium phosphides. The structures of isolated diphosphinoboranes were characterized in the solid state and in solution by means of X-ray diffraction and NMR spectroscopy, respectively. The utility of these...

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