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Description
The high temperature electrical properties of phosphate-iron glasses containing niobium were investigated. Glass samples of the composition of 35P2O5-30Fe2O3-27.5Nb2O5-7.5TiO2 (in %mol) were prepared by the conventional melt quenching technique. Appropriate amounts of reagents ((NH4)2HPO4 (≥99.9%, POCH), Fe2O3 (≥99.9%, POCH), Nb2O5 (≥99.9%, PLUKA AG) and TiO2 (≥99.9%, anatase and rutile mixed, PROLABO)) were thoroughly mixed in an agate mortar and put on electric stove in temperature of 573K in order to carry out the decomposition process of (NH4)2HPO4. Next powders were melted in porcelain crucibles at 1573 K for 1-2 h. The melts were poured on preheated (to 573 K) brass plate and pressed by another plate to obtain flat circular samples (dimensions: 1-2 mm thick, 20-30 mm in diameter). The obtained pellets were annealed at 673 K for 1 h and cooled with furnace. For the electrical measurements gold electrodes were evaporated at the polished samples. Impedance measurements were carried out in the frequency range from 1 mHz to 1 MHz with the ac voltage of 1 Vrms in the temperature range from 363 K to 723 K with the Novocontrol Concept 40 broadband dielectric spectrometer and a high temperature Controller Novotherm HT 1600. The measurements were carried out both while increasing and decreasing the temperature.
Dataset file
hexmd5(md5(part1)+md5(part2)+...)-{parts_count} where a single part of the file is 512 MB in size.Example script for calculation:
https://github.com/antespi/s3md5
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- License:
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CC BYAttribution - Raw data:
- Data contained in dataset was not processed.
Details
- Year of publication:
- 2021
- Verification date:
- 2021-05-24
- Creation date:
- 2014
- Dataset language:
- English
- Fields of science:
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- materials engineering (Engineering and Technology)
- DOI:
- DOI ID 10.34808/7b9v-rj98 open in new tab
- Verified by:
- Gdańsk University of Technology
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