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Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples
Abstract
This manuscript presents a new method for selective extraction and determination of fosetyl-aluminum in fruits and vegetable samples based on ultrasonic-assisted dispersive liquid-liquid microextraction method using ionic liquids (IL-UA-DLLME). A UV-Visible spectrophotometer was used for detection and quantification. Plants used for sample collection were grown under controlled conditions in a greenhouse. Central composite design (CCD)-response surface methodology (RSM) analysis was used for the optimization of significant factors (volume of IL, pH, ultrasonication time, and THF volume). Under optimal conditions, the limit of detection and limit of quantification of the IL-UA-DLLME procedure were 1.5 ng mL−1 and 5.0 ng mL−1 respectively with relative standard deviation 1.9–3.3%. The developed IL-UA-DLLME procedure demonstrated linearity within the concentration range of 5–600 ng mL−1 with an R2 value of 0.9914. The enrichment factor was 114 with a recovery% of 94.2–98.6% (n = 3) at optimal conditions. The IL-UA-DLLME assay was used for the analysis of fosetyl-aluminum in a variety of food samples and was found highly selective and efficient.
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Authors (8)
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Adil Elik
- Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry, Sivas, Turkey
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Hasan Durukan
- Sivas Cumhuriyet University, Department of Plant and Animal Production, Sivas Vocational School of Technical Sciences, Turkey
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Handan Sarac
- Sivas Cumhuriyet University, Department of Plant and Animal Production, Sivas Vocational School of Technical Sciences, Turkey
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Ahmet Demirbas
- Sivas Cumhuriyet University, Department of Plant and Animal Production, Sivas Vocational School of Technical Sciences, Turkey
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Nevcihan Gürsoy
- Sivas Cumhuriyet University, Nanotechnology Engineering, Sivas, Türkiye
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Nail Altunay
- Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry, Sivas, Turkey
Cite as
Full text
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.jfca.2023.105725
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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JOURNAL OF FOOD COMPOSITION AND ANALYSIS
no. 124,
ISSN: 0889-1575 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Haq H., Elik A., Durukan H., Sarac H., Demirbas A., Boczkaj G., Gürsoy N., Altunay N.: Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples// JOURNAL OF FOOD COMPOSITION AND ANALYSIS -Vol. 124, (2023), s.105725-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.jfca.2023.105725
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
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