Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples

Hameed Haq; Adil Elik; Hasan Durukan; Handan Sarac; Ahmet Demirbas; Grzegorz Boczkaj; Nevcihan Gürsoy; Nail Altunay

doi:10.1016/j.jfca.2023.105725

Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples

Abstract

This manuscript presents a new method for selective extraction and determination of fosetyl-aluminum in fruits and vegetable samples based on ultrasonic-assisted dispersive liquid-liquid microextraction method using ionic liquids (IL-UA-DLLME). A UV-Visible spectrophotometer was used for detection and quantification. Plants used for sample collection were grown under controlled conditions in a greenhouse. Central composite design (CCD)-response surface methodology (RSM) analysis was used for the optimization of significant factors (volume of IL, pH, ultrasonication time, and THF volume). Under optimal conditions, the limit of detection and limit of quantification of the IL-UA-DLLME procedure were 1.5 ng mL−1 and 5.0 ng mL−1 respectively with relative standard deviation 1.9–3.3%. The developed IL-UA-DLLME procedure demonstrated linearity within the concentration range of 5–600 ng mL−1 with an R2 value of 0.9914. The enrichment factor was 114 with a recovery% of 94.2–98.6% (n = 3) at optimal conditions. The IL-UA-DLLME assay was used for the analysis of fosetyl-aluminum in a variety of food samples and was found highly selective and efficient.

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Authors (8)

Hameed Haq
Adil Elik
- Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry, Sivas, Turkey
Hasan Durukan
- Sivas Cumhuriyet University, Department of Plant and Animal Production, Sivas Vocational School of Technical Sciences, Turkey
Handan Sarac
- Sivas Cumhuriyet University, Department of Plant and Animal Production, Sivas Vocational School of Technical Sciences, Turkey
Ahmet Demirbas
- Sivas Cumhuriyet University, Department of Plant and Animal Production, Sivas Vocational School of Technical Sciences, Turkey
Grzegorz Boczkaj dr hab. inż.
Nevcihan Gürsoy
- Sivas Cumhuriyet University, Nanotechnology Engineering, Sivas, Türkiye
Nail Altunay
- Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry, Sivas, Turkey

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Articles

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artykuły w czasopismach

Published in:

JOURNAL OF FOOD COMPOSITION AND ANALYSIS no. 124,
ISSN: 0889-1575

Language:

English

Publication year:

2023

Bibliographic description:

Haq H., Elik A., Durukan H., Sarac H., Demirbas A., Boczkaj G., Gürsoy N., Altunay N.: Application of chemometric modeling for ionic liquid-based ultrasonic-assisted dispersive liquid-liquid microextraction: Analysis of fosetyl-aluminum in fruit and vegetable samples// JOURNAL OF FOOD COMPOSITION AND ANALYSIS -Vol. 124, (2023), s.105725-

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