Application of nonmetallic frustrated cations in the activation of small molecules

Kinga Kaniewska-Laskowska; Marcin Czapla; Jarosław Chojnacki; Rafał Grubba

doi:10.1039/d3dt01433a

Application of nonmetallic frustrated cations in the activation of small molecules

Abstract

The concept of nonmetallic frustrated cations has been used in small molecule activation. The in situ generated ambiphilic phosphinoborinium cation activated phenyl isocyanate, diisopropylcarbodiimide, and acetonitrile under very mild conditions without any catalyst, yielding single-, double-, or mixed-activation products. Furthermore, the mechanisms of the reactions of the phosphinoborinium cation with small molecules were elucidated using density functional theory calculations.

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Publication version: Accepted or Published Version
DOI:: Digital Object Identifier (open in new tab) 10.1039/D3DT01433A
License: Copyright (2023 The Royal Society of Chemistry)

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artykuły w czasopismach

Published in:

DALTON TRANSACTIONS no. 52, pages 8311 - 8315,
ISSN: 1477-9226

Language:

English

Publication year:

2023

Bibliographic description:

Kaniewska-Laskowska K., Czapla M., Chojnacki J., Grubba R.: Application of nonmetallic frustrated cations in the activation of small molecules// DALTON TRANSACTIONS -Vol. 52,iss. 24 (2023), s.8311-8315

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