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Effective yttrium based coating for steel interconnects of solid oxide cells: Corrosion evaluation in steam-hydrogen atmosphere

Abstract

This work describes manufacture, analysis and test of a new well conducting corrosion-protection coating that can be applied on steel types with high chromium content. Electrolytic deposition of yttrium salts is used to form thin (<100 nm) coatings on both flat steel sheets (material: Crofer 22 APU) and its properties are proven on woven wire-meshes (materials from two different sources: SUS316 and SUS316L). The oxide scale on the coated Crofer 22 APU sheet remains intact after 2000 h operation at 750 °C in H2 with 90% H2O. The corrosion rate at 750 °C of the coated Crofer 22 APU sheets is compared with that of uncoated samples and of samples with a commercial magneton sputtered CGO coating revealing that the coatings reduce the parabolic rate constant characteristic of the corrosion by a factor of 10 and 20 for the CGO and the Y, respectively.

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Authors (9)

  • Photo of  Å.h. Persson

    Å.h. Persson

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  T.l. Skafte

    T.l. Skafte

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  A.l. Smitshuysen

    A.l. Smitshuysen

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  S.h. Jensen

    S.h. Jensen

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  K. H. Andersen

    K. H. Andersen

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  H. Xu

    H. Xu

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  Ming Chen

    Ming Chen

    • Technical University of Denmark Department of Energy Conversion and Storage
  • Photo of  Peter Vang Hendriksen

    Peter Vang Hendriksen

    • Technical University of Denmark Department of Energy Conversion and Storage

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Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
JOURNAL OF POWER SOURCES no. 440,
ISSN: 0378-7753
Language:
English
Publication year:
2019
Bibliographic description:
Molin S., Persson Å., Skafte T., Smitshuysen A., Jensen S., Andersen K., Xu H., Chen M., Hendriksen P.: Effective yttrium based coating for steel interconnects of solid oxide cells: Corrosion evaluation in steam-hydrogen atmosphere// JOURNAL OF POWER SOURCES -Vol. 440, (2019), s.226814-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jpowsour.2019.226814
Verified by:
Gdańsk University of Technology

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