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Luminescence properties of Eu3+ and Tb3+ doped silica-based xerogels

Abstract

Pure SiO2 xerogels and SiO2 xerogels containing SrF2: Eu3+/: Tb3+ crystals were prepared using sol-gel method. Luminescent spectra showed excitation and emission peaks characteristic to Eu3+ and Tb3+ 4f - 4f transitions. ET Tb3+→Eu3+ has been observed. XRD pattern of SiO2 matrix confirmed lack of long range order. Patterns of SiO2-SrF2:Eu3+ and SiO2-SrF2:Tb3+ showed peaks corresponding to SrF2. SEM images have shown agglomerates of particles and presence of pores. FTIR spectra showed bands related to Si-O vibrations and vibrations associated with the OH groups. Thus, SiO2-SrF2 system doped with Eu3+ and Tb3+ could be a potential candidate for LEDs applications. Review of other materials for LED applications is also presented.

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Category:
Conference activity
Type:
publikacja w wydawnictwie zbiorowym recenzowanym (także w materiałach konferencyjnych)
Title of issue:
EYEC MONOGRAPH 4th European Young Engineers Conference 2015 strony 180 - 193
Language:
English
Publication year:
2015
Bibliographic description:
Walas M., Kościelska B., Lewandowski T., Łapiński M., Sadowski W., Kłonkowski A., Wiczk W., Bylińska I.: Luminescence properties of Eu3+ and Tb3+ doped silica-based xerogels// EYEC MONOGRAPH 4th European Young Engineers Conference 2015/ ed. Michał Wojasiński, Bartosz Nowak Warszawa: Faculty of Chemical and Process Engineering, Warsaw University of Technology, 2015, s.180-193
Verified by:
Gdańsk University of Technology

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