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Phosphanylphosphaalkenes as precursors for metallaphosphaalkene complexes

Abstract

We synthesized phosphanylphosphaalkenes (biph)2C=P-P(tBu)2 (2), Ph2CvP-P(NEt2)2 (3), and (biph)2CvP-P(NEt2)2 (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P–P bond activation and the formation of a bridging phospaalkene complex under mild conditions.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
DALTON TRANSACTIONS no. 53, pages 19107 - 19111,
ISSN: 1477-9226
Language:
English
Publication year:
2024
DOI:
Digital Object Identifier (open in new tab) 10.1039/d4dt03012e
Sources of funding:
  • IDUB
Verified by:
Gdańsk University of Technology

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