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Abstract
The synthesis and ion-binding properties of amide-based derivative of embonic acid andp-aminoazobenzenewere described. The new compound was characterized by X-ray structural analysis and spectroscopic methods.Ligand interacts in acetonitrile with Y-shaped anions (benzoates and acetates) and dihydrogen phosphatesforming complexes of 1:1 stoichiometry. In more polar DMSO the complexes stoichiometry changes to 2:1(L:anion). Light-inducedtranstocisisomerization was studied. The effect of anions on thermal back iso-merization was investigated.
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
no. 390,
ISSN: 1010-6030 - Language:
- English
- Publication year:
- 2020
- Bibliographic description:
- Łukasik N., Chojnacki J., Luboch E., Okuniewski A., Wagner-Wysiecka E.: Photoresponsive, amide-based derivative of embonic acid for anion recognition// JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY -Vol. 390, (2020), s.112307-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.jphotochem.2019.112307
- Sources of funding:
-
- Statutory activity/subsidy
- Verified by:
- Gdańsk University of Technology
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