Synergic Effect of Naphthylated Carbon Nanotubes and Gold Nanoparticles on Catalytic Performance of Hybrid Films Containing Bilirubin Oxidase for the Dioxygen Reduction - Publication - Bridge of Knowledge

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Synergic Effect of Naphthylated Carbon Nanotubes and Gold Nanoparticles on Catalytic Performance of Hybrid Films Containing Bilirubin Oxidase for the Dioxygen Reduction

Abstract

To improve the direct electron transfer from a multicopper oxidase MvBOd to the glassy carbon electrode surface the naphthylated multiwall carbon nanotubes (Napht-MWCNTs) are ombined with gold nanoparticles (AuNPs) to form a conductive network at the electrode and to increase its working surface. Such approach allowed to eliminate the necessity of employing mediators to reach elevated current values. The enzyme stability was improved by accommodating it in a biomimetic film of lipidic liquid-crystalline mesophase of cubic symmetry. The cubic phase hosted the enzyme in its fully active form for days of continuous work of the electrode.

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DOI:
Digital Object Identifier (open in new tab) 10.1002/elan.201600511
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Copyright (2017 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim)

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
ELECTROANALYSIS no. 29, edition 1, pages 103 - 109,
ISSN: 1040-0397
Language:
English
Publication year:
2017
Bibliographic description:
Grippo V., Pawłowska J., Biernat J., Bilewicz R.: Synergic Effect of Naphthylated Carbon Nanotubes and Gold Nanoparticles on Catalytic Performance of Hybrid Films Containing Bilirubin Oxidase for the Dioxygen Reduction// ELECTROANALYSIS. -Vol. 29, iss. 1 (2017), s.103-109
DOI:
Digital Object Identifier (open in new tab) 10.1002/elan.201600511
Verified by:
Gdańsk University of Technology

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