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Abstract
Metathesis reactions between diimido complexes of tungsten(VI)[(ArN)2WCl2] (Ar = 2,6-iPr2C6H3) and lithium derivatives of diphosphanes R2P-P(SiMe3)Li (R = tBu and iPr) yield two anionic diimido complexes of tungsten with side-on bonded phosphanylphosphinidene ligands, [(ArN)2WCl(η2-R2P-P)]-. Both complexes are structurally characterized. A possible reaction mechanism and the role of donor solvents are discussed on the basis of NMR spectroscopic results.
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
no. 2012,
ISSN: 1434-1948 - Language:
- English
- Publication year:
- 2012
- Bibliographic description:
- Grubba R., Kazimierczuk K., Chojnacki J., Pikies J.: Access to Side-On Bonded Tungsten Phosphanylphosphinidene Complexes// EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. -Vol. 2012, nr. iss. 20 (2012),
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/ejic.201200456
- Verified by:
- Gdańsk University of Technology
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