Search
Bis(diethylamido-[kappa]N)(diethylamine-[kappa]N)bis(2,6-diisopropylphenylamido-[kappa]N)zirconium(IV)
Abstract
In the title compound, [Zr(C12H18N)2(C4H10N)2(C4H11N)] or [Zr(HNC6H3iPr2)2(NEt2)2(HNEt2)], which was obtained by the reaction of Zr(NEt)4 with iPr2C6H3NH2, the Zr IV atom is in a trigonal–bipiramidal geometry in which the N atoms from two iPr2C6H3NH and one NEt2 ligand occupy the equatorial positions, and the N atoms of an NEt2 and an Et2NH ligand occupy the apical positions. An intramolecular N—HN contact occurs. There are two independent molecules in the asymmetric unit.
Authors (4)
Cite as
Full text
download paper
downloaded 1 times
- Publication version
- Accepted or Published Version
- License
-
open in new tab
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach recenzowanych i innych wydawnictwach ciągłych
- Published in:
-
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
no. 69,
ISSN: 1600-5368 - Language:
- English
- Publication year:
- 2013
- Bibliographic description:
- Zauliczny M., Grubba R., Ponikiewski Ł., Pikies J.: Bis(diethylamido-[kappa]N)(diethylamine-[kappa]N)bis(2,6-diisopropylphenylamido-[kappa]N)zirconium(IV)// ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. -Vol. 69., (2013),
- Verified by:
- Gdańsk University of Technology
seen 67 times