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Cathodically activated Au/TiO2 nanocomposite synthesized by a new facile solvothermal method: An efficient electrocatalyst with Pt-like activity for hydrogen generation
Abstract
We report here a facile, template-free and one-step solvothermal approach for the synthesis of high-temperature stable gold/titania nanocomposite (NCs), providing a new, simple, quick and inexpensive wet-chemical route. Our approach is based on the assembly of gold salt and titanium butoxide in dimethyl sulfoxide (DMSO). Also, we present here, for the first time, a cathodically activated Au/TiO2 catalyst with Pt/C activity for the hydrogen evolution reaction (HER) in 0.5 M H2SO4 in the dark. The as-prepared (unactivated) Au/TiO2 NCs exhibits considerable electrocatalytic activity for H2 generation in the dark, with a low onset potential (EHER) of −64 mV vs. RHE, a Tafel slope (-bc) of 60 mV dec−1 and an exchange current density (jo) of 0.12 mA cm−2. Long-term stability and durability tests in 0.5 M H2SO4, employing cyclic voltammetry technique (10,000 of repetitive cycling) and 72 h of chronoamperometry measurements at a high cathodic potential (cathodic activation), reveal that the electrocatalyst activates during such aging processes yielding an activated Au/TiO2 catalyst with Pt/C-like activity for H2 generation (EHER -3 mV, -bc: 35 mV dec−1, and jo: 0.95 mA cm−2). The outstanding HER activity of the activated catalyst is discussed.
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Authors (9)
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A. Mezni
- Taif University Department of Chemistry
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Mohamed Ibrahim
- Taif University Department of Chemistry
-
M. El-kemary
- Kafrelsheikh University Chemistry Department
-
A. Shaltout
- Taif University Physics Department
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Nasser Mostafa Ph.D.
- Taif University Department of Chemistry
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T. Kumeria
- The University of Queensland School of Pharmacy
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T. Altalhi
- Taif University Department of Chemistry
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Mohammed Amin Prof.
- Taif University Department of Chemistry
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
ELECTROCHIMICA ACTA
no. 290,
pages 404 - 418,
ISSN: 0013-4686 - Language:
- English
- Publication year:
- 2018
- Bibliographic description:
- Mezni, A., Ibrahim M., El-Kemary, M., Shaltout, A., Mostafa N., Ryl J., Kumeria, T., Altalhi, T., Amin M.: Cathodically activated Au/TiO2 nanocomposite synthesized by a new facile solvothermal method: An efficient electrocatalyst with Pt-like activity for hydrogen generation// ELECTROCHIMICA ACTA. -Vol. 290, (2018), s.404-418
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.electacta.2018.08.083
- Verified by:
- Gdańsk University of Technology
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