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Abstract
Rate coefficients for the formation of carbon monoxide (CO) by radiative association of carbon and oxygen atoms are computed using quantum dynamical simulations. At temperatures above 10 K CO radiative association is dominated by C(3P) and O(3P) approaching on the A1Π potential energy curve. The rate coefficient is estimated as k=A(T/300 K)αexp−β/T with A= 1.39 × 10−18 cm3 s−1, α=−0.016 and β= 92.2 for temperatures between 6 and 127.2 K, and A= 1.36 × 10−17 cm3 s−1, α= 0.41 and β= 340 for temperatures between 127.2 and 15 000 K. Furthermore we computed the rate coefficients for approaching on the X1Σ+ curve. For temperatures below 200 K it is between 0.7 × 10−22 and 4 × 10−22 cm3 s−1.
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Authors (3)
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-
Magnus Gustafsson
- University of Gothenburg Department of Chemistry and Molecular Biology
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Gunnar Nyman
- University of Gothenburg Department of Chemistry and Molecular Biology
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1111/j.1365-2966.2011.18654.x
- License
- Copyright (2011 RAS)
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY
no. 414,
edition 4,
pages 3547 - 3550,
ISSN: 0035-8711 - Language:
- English
- Publication year:
- 2011
- Bibliographic description:
- Franz J., Gustafsson M., Nyman G.: Formation of carbon monoxide by radiative association: a quantum dynamical study// MONTHLY NOTICES OF THE ROYAL ASTRONOMICAL SOCIETY. -Vol. 414, iss. 4 (2011), s.3547-3550
- DOI:
- Digital Object Identifier (open in new tab) 10.1111/j.1365-2966.2011.18654.x
- Verified by:
- Gdańsk University of Technology
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