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Hydrogen Bonds in Blends of Poly(N-isopropylacrylamide), Poly(N-ethylacrylamide) Homopolymers, and Carboxymethyl Cellulose
Abstract
Recently, it was reported that the physical crosslinking exhibited by some biopolymers could provide multiple benefits to biomedical applications. In particular, grafting thermoresponsive polymers onto biopolymers may enhance the degradability or offer other features, as thermothickening behavior. Thus, different interactions will affect the different hydrogen bonds and interactions from the physical crosslinking of carboxymethyl cellulose, the lower critical solution temperatures (LCSTs), and the presence of the ions. This work focuses on the study of blends composed of poly(N-isopropylacrylamide), poly(N-ethylacrylamide), and carboxymethyl cellulose in water and water/methanol. The molecular features, thermoresponsive behavior, and gelation phenomena are deeply studied. The ratio defined by both homopolymers will alter the final properties and the gelation of the final structures, showing that the presence of the hydrophilic groups modifies the number and contributions of the diverse hydrogen bonds.
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Authors (6)
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Alberto García-Peñas
- College of Materials Science and Engineering, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen Key Laboratory of Polymer Science and Technology,
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Weijun Liang
- College of Materials Science and Engineering, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen Key Laboratory of Polymer Science and Technology,
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Saud Hashmi
- Department of Polymer and Petrochemical Engineering, NED University of Engineering and Technology, University Road, Karachi 75270, Pakistan
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Gaurav Sharma
- International Research Centre of Nanotechnology for Himalayan Sustainability (IRCNHS), Shoolini University, Solan 173212, Himachal Pradesh, India
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Florian J. Stadler
- College of Materials Science and Engineering, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Laboratory for Biopolymers and Safety Evaluation, Shenzhen Key Laboratory of Polymer Science and Technology,
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/jcs5090240
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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Journal of Composites Science
no. 5,
ISSN: - Language:
- English
- Publication year:
- 2021
- Bibliographic description:
- García-Peñas A., Liang W., Hashmi S., Sharma G., Saeb M., Stadler F. J.: Hydrogen Bonds in Blends of Poly(N-isopropylacrylamide), Poly(N-ethylacrylamide) Homopolymers, and Carboxymethyl Cellulose// Journal of Composites Science -Vol. 5,iss. 9 (2021), s.240-
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/jcs5090240
- Verified by:
- Gdańsk University of Technology
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