Hydrothermal Cobalt Doping of Titanium Dioxide Nanotubes towards Photoanode Activity Enhancement - Publication - Bridge of Knowledge

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Hydrothermal Cobalt Doping of Titanium Dioxide Nanotubes towards Photoanode Activity Enhancement

Abstract

Doping and modification of TiO2 nanotubes were carried out using the hydrothermal method. The introduction of small amounts of cobalt (0.1 at %) into the structure of anatase caused an increase in the absorption of light in the visible spectrum, changes in the position of the flat band potential, a decrease in the threshold potential of water oxidation in the dark, and a significant increase in the anode photocurrent. The material was characterized by the SEM, EDX, and XRD methods, Raman spectroscopy, XPS, and UV-Vis reflectance measurements. Electrochemical measurement was used along with a number of electrochemical methods: chronoamperometry, electrochemical impedance spectroscopy, cyclic voltammetry, and linear sweep voltammetry in dark conditions and under solar light illumination. Improved photoelectrocatalytic activity of cobalt-doped TiO2 nanotubes is achieved mainly due to its regular nanostructure and real surface area increase, as well as improved visible light absorption for an appropriate dopant concentration

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
Materials no. 14,
ISSN: 1996-1944
Language:
English
Publication year:
2021
Bibliographic description:
Wtulich M., Szkoda M., Gajowiec G., Gazda M., Jurak K., Sawczak M., Lisowska-Oleksiak A.: Hydrothermal Cobalt Doping of Titanium Dioxide Nanotubes towards Photoanode Activity Enhancement// Materials -Vol. 14,iss. 6 (2021), s.1507-
DOI:
Digital Object Identifier (open in new tab) 10.3390/ma14061507
Verified by:
Gdańsk University of Technology

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