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Insights into Seawater Biodegradation of Sustainable Mater-Bi/Poly(ε-caprolactone)-Based Biocomposites Filled with Diisocyanate-Modified Cellulose Particles
Abstract
: Due to rapid economic growth, the use of plastics in almost all areas of human life has significantly increased over recent decades, leading to massive pollution. Therefore, works dealing with sustainable and biodegradable polymer materials are vital now. Herein, sustainable MaterBi/poly(ε-caprolactone) (PCL)-based biocomposites, filled with diisocyanate-modified cellulose particles, were prepared and subjected to 12-week seawater degradation. Changes in the chemical structure and surface wettability pointed to the increasing hydrophilicity of materials over time, which was limited by diisocyanate modifications. Only minor changes in the thermal performance of analyzed materials have been observed, pointing to the limited biodegradation of the PCL phase. The most significant effects have been related to the composite yellowing due to the filler diisocyanate modifications and surface erosion increasing its roughness. Obtained results pointing to the low degradation rate bring into question the commonly-regarded biodegradable nature of PCL material.
Citations
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Authors (4)
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Aleksander Hejna dr inż.
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Olga Mysiukiewicz
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Mateusz Barczewski
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Full text
- Publication version
- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/environments10050090
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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Environments
no. 10,
ISSN: 2076-3298 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Hejna A., Kosmela P., Mysiukiewicz O., Barczewski M.: Insights into Seawater Biodegradation of Sustainable Mater-Bi/Poly(ε-caprolactone)-Based Biocomposites Filled with Diisocyanate-Modified Cellulose Particles// Environments -,iss. 10(5) (2023), s.1-12
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/environments10050090
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
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