Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex

Piotr Maślewski; Katarzyna Kazimierczuk; Zbigniew Hnatejko; Anna Dołęga

doi:10.1016/j.ica.2017.01.014

Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex

Abstract

Two dinuclear complexes of zinc and cadmium with silanethiolate and bridging biimidazole ligands are characterized by X-ray diffraction, FT-IR, UV–Vis and emission spectroscopies. The complexes 1 (Zn) and 2 (Cd) are isostructural but exhibit different electronic structures and different character of frontier HOMO orbitals as indicated by DFT calculations. Lluminescence studies prove strong emission properties of zinc complex.

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Authors (4)

Piotr Maślewski
Katarzyna Kazimierczuk dr hab.
Zbigniew Hnatejko dr hab.
- University in Poznań .
Anna Dołęga prof. dr hab. inż.

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Category:: Articles
Type:: artykuł w czasopiśmie wyróżnionym w JCR
Published in:: INORGANICA CHIMICA ACTA no. 459, pages 22 - 28,
ISSN: 0020-1693
Language:: English
Publication year:: 2017
Bibliographic description:: Maślewski P., Kazimierczuk K., Hnatejko Z., Dołęga A.: Isostructural zinc and cadmium silanethiolates with bridging biimidazole co-ligands – Enhanced luminescence of zinc complex// INORGANICA CHIMICA ACTA. -Vol. 459, (2017), s.22-28
DOI:: Digital Object Identifier (open in new tab) 10.1016/j.ica.2017.01.014
Verified by:: Gdańsk University of Technology