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Reactions of methyl radicals with silica supported silver nanoparticles in aqueous solutions

Abstract

Silica supported silver nanoparticles (Ag°–SiO2 –NCs, NCs=nanocomposites) suspended in aqueous solutions are efficient catalysts for the dimerization of methyl radicals to produce ethane, while bare silica is quite inert towards the interaction with methyl radicals. In the presence of small amounts of ethanol adsorbed on the SiO2 surface, the reaction path with methyl radicals is changed and methane is formed as the major product.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
RADIATION PHYSICS AND CHEMISTRY no. 124, pages 41 - 45,
ISSN: 0969-806X
Language:
English
Publication year:
2016
Bibliographic description:
Zidki T., Haenel A., Bar-Ziv R.: Reactions of methyl radicals with silica supported silver nanoparticles in aqueous solutions// RADIATION PHYSICS AND CHEMISTRY. -Vol. 124, (2016), s.41-45
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.radphyschem.2015.11.027
Verified by:
Gdańsk University of Technology

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