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Synthesis and properties of new 'N,'N-phenyltetrazole podand

Abstract

The synthesis of a new chromogenic N,N-phenyltetrazole receptor is reported here. The cationbinding properties of this receptor in solution were investigated by naked-eye colour change, electrochemical methods and UV-Vis spectroscopy in various solvents (CH3CN, dimethylsulphoxide (DMSO), DMSO/H2O, CH3CN/H2O and CH3CN/MeOH). In addition, the receptor was used as a sensing material in ion-selective membrane electrodes. The selectivity and sensitivity of these electrodes towards alkali, alkali-earth, transition and heavy metal cations in aqueous solution were tested. The relation between the carrier structure and membrane plasticisers was investigated.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
CHEMICAL PAPERS no. 70, edition 3, pages 253 - 264,
ISSN: 0366-6352
Language:
English
Publication year:
2016
Bibliographic description:
Pazik A., Kamińska B., Skwierawska A., Nakonieczna S., Ossowski T.: Synthesis and properties of new 'N,'N-phenyltetrazole podand// CHEMICAL PAPERS. -Vol. 70, iss. 3 (2016), s.253-264
DOI:
Digital Object Identifier (open in new tab) 10.1515/chempap-2015-0209
Verified by:
Gdańsk University of Technology

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