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Thermodynamic Properties of Inorganic Salts in Nonaqueous Solvents. VI. Apparent Molar Volumes, Expansibilities, and Compressibilities of Divalent Transition Metal Ions in Methanol and Dimethylsulfoxide
Abstract
The temperature dependence of the density of divalent transition metal perchlorates in dimethylsulfoxide as well as cobalt(II), nickel(II) perchlorates, and copper(II) trifluoromethanesulfonate in methanol was determined. Moreover, sound velocities for solutions of cobalt(II), nickel(II) perchlorates, and copper(II) trifluoromethanesulfonate in methanol have been measured at 298.15 K. From these data, the partial molar volumes, partial molar expansibilities, and partial molar isentropic compressibilities have been estimated. The results obtained are discussed in terms of ion-solvent interactions.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
JOURNAL OF CHEMICAL AND ENGINEERING DATA
no. 55,
pages 2116 - 2122,
ISSN: 0021-9568 - Language:
- English
- Publication year:
- 2010
- Bibliographic description:
- Warmińska D., Wawer J., Grzybkowski W.: Thermodynamic Properties of Inorganic Salts in Nonaqueous Solvents. VI. Apparent Molar Volumes, Expansibilities, and Compressibilities of Divalent Transition Metal Ions in Methanol and Dimethylsulfoxide// JOURNAL OF CHEMICAL AND ENGINEERING DATA. -Vol. 55, nr. iss. 6 (2010), s.2116-2122
- Verified by:
- Gdańsk University of Technology
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