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Search results for: GREEN MOF

  • Metal-Organic Frameworks in Green Analytical Chemistry

    Publication

    - Year 2023

    Taking into consideration the rapid expansion of MOFs applications in the analytical chemistry area, it is important to evaluate the existing and future analytical MOF-based methods according to GAC principles. From this point of view, eco-friendly MOFs-based methods should include features such as: green design and synthesis of MOF, evaluation of toxicity issues of MOFs, and incorporation of MOFs in GAC methods. This Chapter will...

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  • Fabrication of Gold and Silver Nanoparticles Supported on Zinc Imidazolate Metal–Organic Frameworks as Active Catalysts for Hydrogen Release from Ammonia Borane

    Publication
    • E. S. Souza
    • M. A. de Oliveira
    • J. d. J. Santana
    • N. Łukasik
    • O. M. M. Madeiro da Costa
    • L. C. Almeida
    • B. Barros
    • J. Kulesza

    - ACS Omega - Year 2024

    Well-dispersed Au and Ag nanoparticles (NPs) have been immobilized on a zinc imidazolate metal−organic framework, Zn(mim), using the “one-pot” method and tested as catalysts in ammonia borane hydrolysis. The AuNPs@Zn(mim) and AgNPs@Zn(mim) materials were characterized by FTIR, XRD, ICP-OES, TGA, BET, SEM, and TEM. The AgNPs@Zn(mim) catalyst showed a high yield (98.5%) and high hydrogen generation rate (3352.71 mL min−1 gAg−1) in...

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  • Synthesis of green benzamide-decorated UiO-66-NH2 for biomedical applications

    Publication
    • N. Rabiee
    • A. M. Ghadiri
    • V. Alinezhad
    • A. Sedaghat
    • S. Ahmadi
    • Y. Fatahi
    • P. Makvandi
    • M. Saeb
    • M. Bagherzadeh
    • M. Asadnia... and 2 others

    - CHEMOSPHERE - Year 2022

    Metal-organic frameworks (MOFs) biocompatible systems can host enzymes/bacteria/viruses. Herein we synthesized a series of fatty acid amide hydrolase (FAAH)-decorated UiO-66-NH2 based on Citrus tangerine leaf extract for drug delivery and biosensor applications. Five chemically manipulated FAAH-like benzamides were localized on the UiO-66-NH2 surface with physical interactions. Comprehensive cellular and molecular analyses were...

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  • Mission impossible for cellular internalization: When porphyrin alliance with UiO-66-NH2 MOF gives the cell lines a ride

    Publication
    • S. Ahmadi
    • V. Jajarmi
    • M. Ashrafizadeh
    • A. Zarrabi
    • J. T. Haponiuk
    • M. Saeb
    • E. C. Lima
    • M. Rabiee
    • N. Rabiee

    - JOURNAL OF HAZARDOUS MATERIALS - Year 2022

    Is it possible to accelerate cell internalization by hybridization of nanomaterials? Herein we support the realization of using metal-organic frameworks (MOFs) with the assistance of rigid porphyrin structure (H2TMP) aimed at drug loading, drug release, relative cell viability, and targeted in vitro drug delivery. There are several MOFs, i.e., UiO-66-NH2 (125 ± 12.5 nm), UiO-66-NH2 @H2TMP (160 ± 14 nm), UiO-66-NH2 @H2TMP@DOX, and...

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