Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels - Publikacja - MOST Wiedzy

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Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels

Abstrakt

Biowaste chicken eggshell (ES) powder was applied as a potential cure modifier in epoxy/anhydride systems. Cure behaviour and kinetics of composites filled with very low content (0.1 wt% based on epoxy resin) of ES, calcium carbonate (CaCO3), and terpolymer-modified fillers, mES and mCaCO3, were discussed comparatively. Surface analysis was performed by X-ray photoelectron spectroscopy. Cure kinetics was investigated by differential (Friedman) and integral (Ozawa and Kissinger–Akahira–Sunose) isoconversional methods using dynamic differential scanning calorimetry (DSC) data. Overall, protein precursors naturally existing in the structure of pristine ES facilitated crosslinking of epoxy and hardener of anhydride with functional groups resulting from terpolymer attachment to CaCO3 particles. Accelerated/hindered cure was observed depending on the filler type and surface characteristics, as investigated via the autocatalytic/non-catalytic nature of reactions and comparison of activation energy values of four types of composites. An enhanced cure was identified for composites containing untreated ES, which could be inferred on account of the lower competitive cure of carboxyl groups in the terpolymer backbone with epoxy compared to peptide groups existing in microporous pristine ES. On the other hand, mCaCO3 revealed low values of activation energy compared to pristine CaCO3, but still of the same order as ground biowaste ES.

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Autorzy (11)

  • Zdjęcie użytkownika  Mohammad Saeb

    Mohammad Saeb

    • Institute for Color Science and Technology, Tehran, Iran Department of Resin and Additives
  • Zdjęcie użytkownika  Mehdi Ghaffari

    Mehdi Ghaffari

    • Golestan University, Gorgan, Iran Department of Polymer
  • Zdjęcie użytkownika  Hadi Rastin

    Hadi Rastin

    • University of Tehran, Tehran, Iran School of Chemical Engineering, College of Engineering
  • Zdjęcie użytkownika  Hossein Khonakdar

    Hossein Khonakdar

    • Leibniz-Institut für Polymerforschung Dresden e.V., Dresden, Germany Institute of Polymer Research
  • Zdjęcie użytkownika  Frank Simon

    Frank Simon

    • Leibniz-Institut für Polymerforschung Dresden e.V., Dresden, German Institute of Polymer Research
  • Zdjęcie użytkownika  Farhood Najafi

    Farhood Najafi

    • Institute for Color Science and Technology, Tehran, Iran Department of Resin and Additives
  • Zdjęcie użytkownika  Vahabodin Goodarzi

    Vahabodin Goodarzi

    • Baqiyatallah University of Medical Sciences,Tehran, Iran Applied Biotechnology Research Center,
  • Zdjęcie użytkownika  Poornima Vijayan

    Poornima Vijayan

    • Qatar University, Doha, Qatar Center for Advanced Materials
  • Zdjęcie użytkownika  Debora Puglia

    Debora Puglia

    • University of Perugia, Terni, Italy Materials Engineering Centre, Department of Civil and Environmental Engineering
  • Zdjęcie użytkownika  Farzaneh Asl

    Farzaneh Asl

    • University of Tehran, Tehran, Iran School of Chemical Engineering, College of Engineering

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Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
RSC Advances nr 7, strony 2218 - 2230,
ISSN: 2046-2069
Język:
angielski
Rok wydania:
2017
Opis bibliograficzny:
Saeb M., Ghaffari M., Rastin H., Khonakdar H., Simon F., Najafi F., Goodarzi V., Vijayan P., Puglia D., Asl F., Formela K.: Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels// RSC Advances. -Vol. 7, (2017), s.2218-2230
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1039/c6ra24772e
Weryfikacja:
Politechnika Gdańska

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