Wyszukiwarka
Electrochemical determination of neurotransmitter serotonin using boron/nitrogen co-doped diamond-graphene nanowall-structured particles
Abstrakt
Electrode fouling is a major issue in biological detection due to the adhesion of the protein itself and polymerization of biomolecules on the electrode surface, impeding the electron transfer ability and decreasing the current response. To overcome this issue, the use of anti-fouling material, especially boron-doped diamond (BDD) electrode, is an alternative way. However, the electrocatalytic activity of BDD is inadequate compared with graphene nanowalls, or other sp2 phase materials. Furthermore, the contamination from other metals during the synthesis of BDD can affect the electrochemical analysis. Herein, for the first time, we report boron/nitrogen co-doped with diamond graphene nanowalls (DGNW) integrated with the screen-printed graphene electrode (SPGE) for the detection of serotonin (5-HT) as a model system. DGNW shows the integration of sp2 and sp3 hybridized phases, leading to a high surface area, high electrocatalytic activity, wide potential window, and a low background current. DGNWs prepared under different conditions were investigated and characterized. Compared to the bare SPGEs, the DGNW modified electrode exhibited good electrochemical performance and a superior anti-fouling ability for neurotransmitter detection. A significant enhancement in current response in a concentration-dependent manner was obtained using differential pulse voltammetry (DPV) in the presence of 5-HT from 1 to 500 μM (R2 > 0.99) with a low detection limit (0.28 μM). Moreover, this proposed method was applied in a synthetic urine sample to confirm its biological applicability. These results show that the DGNW modified electrode could be productively utilized as an alternative electrochemical transducer with a good anti-fouling performance.
Cytowania
-
1 6
CrossRef
-
0
Web of Science
-
1 4
Scopus
Autorzy (5)
-
Suchanat Boonkaew
-
Martin Jönsson-Niedziółka
Cytuj jako
Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.jelechem.2022.116938
- Licencja
-
otwiera się w nowej karcie
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
-
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
nr 926,
ISSN: 1572-6657 - Język:
- angielski
- Rok wydania:
- 2022
- Opis bibliograficzny:
- Boonkaew S., Dettlaff A., Sobaszek M., Bogdanowicz R., Jönsson-Niedziółka M.: Electrochemical determination of neurotransmitter serotonin using boron/nitrogen co-doped diamond-graphene nanowall-structured particles// JOURNAL OF ELECTROANALYTICAL CHEMISTRY -Vol. 926, (2022), s.116938-
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.jelechem.2022.116938
- Źródła finansowania:
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 102 razy
Publikacje, które mogą cię zainteresować
3D Hierarchical Boron-Doped Diamond-Multilayered Graphene Nanowalls as an Efficient Supercapacitor Electrode
- D. Banerjee,
- S. Kamatchi,
- D. Sujit
- + 10 autorów
Comparison of the paracetamol electrochemical determination using boron-doped diamond electrode and boron-doped carbon nanowalls
- P. Niedziałkowski,
- Z. Celuba,
- N. Malinowska
- + 6 autorów
Schottky Junction-Driven Photocatalytic Effect in Boron-Doped Diamond-Graphene Core–Shell Nanoarchitectures: An sp3/sp2 Framework for Environmental Remediation
- S. K. Ghadei,
- M. Ficek,
- S. K. Sethy
- + 5 autorów
Diamondized carbon nanoarchitectures as electrocatalytic material for sulfate-based oxidizing species electrogeneration
- K. C. de Freitas Araújo,
- E. Vieira dos Santos,
- M. Pierpaoli
- + 4 autorów