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Pressure-induced flow processing behind the superior mechanical properties and heat-resistance performance of poly(butylene succinate)
Abstrakt
We propose a pressure-induced flow (PIF) processing method for the simultaneous enhancement of strength, toughness, and heat resistance of biodegradable poly(butylene succinate) (PBS). The pressure and temperature were systematically adjusted to optimize the tensile strength of PBS. Under the optimized processing conditions, the structured PBS was characterized by relatively high strength of 89.5 MPa, toughness of 21.4 kJ·m−2 , and improved heat resistance without deterioration of much of its ductility. Microscopic analyses witnessed denser and highly oriented crystalline domains along the flow direction caused by PIF processing. Detailed crystallization analysis made by 2D-WAXD and 2D-SAXS unraveled the extremely ordered PBS domains, which were featured by a significant increase in the orientation degree from 0.25 for the reference to 0.73 for PIF-processed PBS. Such a highly ordered microstructure substantially boosted the degree of crystallinity and heatresistance temperature of PBS. We believe that our findings would offer a facile, green, and cost-effective approach for fabricating biodegradable polymers with outstanding properties and performance.
Cytowania
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9
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Web of Science
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Autorzy (8)
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Tairong Kuang
- Zhejiang University of Technology
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Runhang Zeng
- Zhejiang University of Technology
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Bozhen Wu
- Zhejiang University of Technology
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Feng Chen
- Zhejiang University of Technology
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Tong Liu
- Zhejiang University of Technology
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Mingqiang Zhong
- Zhejiang University of Technology
Cytuj jako
Pełna treść
- Wersja publikacji
- Accepted albo Published Version
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1515/epoly-2022-0018
- Licencja
-
otwiera się w nowej karcie
Słowa kluczowe
Informacje szczegółowe
- Kategoria:
- Publikacja w czasopiśmie
- Typ:
- artykuły w czasopismach
- Opublikowano w:
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E-POLYMERS
nr 22,
strony 156 - 164,
ISSN: 1618-7229 - Język:
- angielski
- Rok wydania:
- 2022
- Opis bibliograficzny:
- Kuang T., Zeng R., Hejna A., Saeb M., Wu B., Chen F., Liu T., Zhong M.: Pressure-induced flow processing behind the superior mechanical properties and heat-resistance performance of poly(butylene succinate)// E-POLYMERS -Vol. 22,iss. 1 (2022), s.156-164
- DOI:
- Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1515/epoly-2022-0018
- Weryfikacja:
- Politechnika Gdańska
wyświetlono 101 razy
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