Sample preparation procedure for the determination of polycyclic aromatic hydrocarbons in petroleum vacuum residue and bitumen - Publikacja - MOST Wiedzy

Twoje konto

zaloguj

Wyszukiwarka

Sample preparation procedure for the determination of polycyclic aromatic hydrocarbons in petroleum vacuum residue and bitumen

Abstrakt

This paper describes a novel method of samplepreparation for the determination of trace concentrations ofpolycyclic aromatic hydrocarbons (PAHs) in high-boilingpetroleum products. Limits of quantitation of the investigatedPAHs in materials of this type range from tens ofnanograms per kilogram to <20 μg/kg. The studies revealedthat in order to separate most of interferences from theanalytes without a significant loss of PAHs, it is necessaryto use size exclusion chromatography as the first step ofsample preparation, followed by adsorption using normalphaseliquid chromatography. The use of orthogonalseparation procedure described in the paper allows theisolation of only a group of unsubstituted and substitutedaromatic hydrocarbons with a specific range of molar mass.The lower the required limit of quantitation of PAHs, thelarger is the scale of preparative liquid chromatography inboth steps of sample preparation needed. The use ofinternal standard allows quantitative results to be correctedfor the degree of recovery of PAHs during the samplepreparation step. Final determination can be carried outusing HPLC-FLD, GC-MS, or HPLC-UV-VIS/DAD. Thelast technique provides a degree of identification throughthe acquired UV-VIS spectra.

Cytowania

  • 4 0

    CrossRef

  • 0

    Web of Science

  • 4 0

    Scopus

Autorzy (4)

Cytuj jako

Pełna treść

pobierz publikację
pobrano 22 razy
Wersja publikacji
Accepted albo Published Version
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s00216-011-5134-9
Licencja
Creative Commons: CC-BY otwiera się w nowej karcie

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
ANALYTICAL AND BIOANALYTICAL CHEMISTRY nr 401, strony 1059 - 1069,
ISSN: 1618-2642
Język:
angielski
Rok wydania:
2011
Opis bibliograficzny:
Gilgenast-Krasińska E., Boczkaj G., Przyjazny A., Kamiński M.: Sample preparation procedure for the determination of polycyclic aromatic hydrocarbons in petroleum vacuum residue and bitumen// ANALYTICAL AND BIOANALYTICAL CHEMISTRY. -Vol. 401, nr. No. 3 (2011), s.1059-1069
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s00216-011-5134-9
Weryfikacja:
Politechnika Gdańska

wyświetlono 122 razy

Publikacje, które mogą cię zainteresować

Determination of parent and methylated polycyclic aromatic hydrocarbons in water samples by dispersive liquid–liquid microextraction–two dimensional gas chromatography–time-of-flight mass spectrometry

2014

Determination of polycyclic aromatic hydrocarbons (PAHs) and other organic pollutants in freshwaters on the western shore of Admiralty Bay (King George Island, Maritime Antarctica).

2019

Determination of fuel combustion product in airport runoff water samples using liquid–liquid extraction with gas chromatography–spectrometry

2016

Selected concentration techniques for gas chromatographic analysis of environmental samples

2002
Meta Tagi