Stabilities of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry - Publikacja - MOST Wiedzy

Twoje konto

zaloguj

Wyszukiwarka

Stabilities of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry

Abstrakt

Bisphenol A diglycidyl ether (BADGE), bisphenol F diglycydyl ether (BFDGE), and their related compounds are widely used as precursors in production of epoxy resins. The high reactivity of these compounds makes the development of analytical methodologies that ensure appropriate metrological accuracy crucial. Consequently, we aimed to determine whether and to what extent the composition of the solution and storage conditions affect the stability of selected BADGE and BFDGE derivatives. The stabilities of these compounds were studied using liquid chromatography–tandem mass spectrometry with electrospray ionization (HPLC-ESI–MS/MS). The chromatographic method elaborated here has allowed for separation of the analytes in time shorter than 6 min, for both methanol and acetonitrile-based mobile phases. The obtained calibration curves for all analytes were linear in the range tested. The values of limit of detection (LODs) were in the range of 0.91–2.7 ng/mL, while values of limit of quantitation (LOQs) were in the range of 2.7–5.7 ng/mL. The chosen experimental conditions were compared in terms of the content of organic solvent in solution, storage temperature, and time. Our results show that the content of BADGE, BADGE·HCl, BFDGE, three-ring NOGE decreased with increasing water content (> 40% v/v). For BADGE and three-ring NOGE, significant changes in concentration were noted as early as 24 h after the test solutions had been prepared. In addition, a reduction in the storage temperature (4 to − 20 °C) reduced the rate of transformation of the monitored analytes. Our study will increase quality control in future research and may increase the reliability of the obtained results.

Cytowania

  • 1 4

    CrossRef

  • 0

    Web of Science

  • 1 9

    Scopus

Autorzy (5)

Cytuj jako

Pełna treść

pobierz publikację
pobrano 120 razy
Wersja publikacji
Accepted albo Published Version
Licencja
Creative Commons: CC-BY otwiera się w nowej karcie

Słowa kluczowe

Informacje szczegółowe

Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
ANALYTICAL AND BIOANALYTICAL CHEMISTRY nr 411, strony 6387 - 6398,
ISSN: 1618-2642
Język:
angielski
Rok wydania:
2019
Opis bibliograficzny:
Jatkowska N., Kubica P., Kudłak B., Namieśnik J., Wasik A.: Stabilities of bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, and their derivatives under controlled conditions analyzed using liquid chromatography coupled with tandem mass spectrometry// ANALYTICAL AND BIOANALYTICAL CHEMISTRY. -Vol. 411, iss. 24 (2019), s.6387-6398
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1007/s00216-019-02016-5
Źródła finansowania:
Weryfikacja:
Politechnika Gdańska

wyświetlono 221 razy

Publikacje, które mogą cię zainteresować

Ultrasound assisted solvent extraction of porous membrane-packed samples followed by liquid chromatography-tandem mass spectrometry for determination of BADGE, BFDGE and their derivatives in packed vegetables

2020

Influence of Storage Time and Temperature on the Toxicity, Endocrine Potential, and Migration of Epoxy Resin Precursors in Extracts of Food Packaging Materials

2019

Assessing ecotoxicity and the endocrine potential of selected phthalates, BADGE and BFDGE derivatives in relation to environmentally detectable levels

2018

Bisphenols and their derivatives in baby diaper samples.

2023
Meta Tagi