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Synthesis of Phosphonated Carbon Nanotubes: New Insight into Carbon Nanotubes Functionalization

Abstrakt

Carbon nanotubes were successfully functionalized for the first time in a free radical phosphonylation reaction. Three synthetic protocols were proposed. Carbon nanotubes and diethylphosphite reacted in the presence of known radical initiator, such as azobisisobutyronitrile, single electron oxidant—Mn(OAc)3, or under UV radiation. The functionalized material was fully characterized by means of spectroscopic methods, together with microscopic, surface area and thermogravimetric analyses. UV-illumination was found to be the most effective approach for introducing phosphonates onto carbon nanotubes. X-ray photoelectron spectroscopy analysis showed 6% phosphorus in this sample. Moreover, the method was performed at room temperature for only one hour, using diethylphosphite as a reactant and as a solvent. The functionalized carbon nanotubes showed an improved thermal stability, with a decomposition onset temperature increase of more than 130 °C. This makes it very promising material for flame retarding applications.

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Wersja publikacji
Accepted albo Published Version
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Creative Commons: CC-BY otwiera się w nowej karcie

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuły w czasopismach
Opublikowano w:
Materials nr 14,
ISSN: 1996-1944
Język:
angielski
Rok wydania:
2021
Opis bibliograficzny:
Nadolska M., Prześniak-Welenc M., Łapiński M., Sadowska K.: Synthesis of Phosphonated Carbon Nanotubes: New Insight into Carbon Nanotubes Functionalization// Materials -Vol. 14,iss. 11 (2021), s.2726-
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.3390/ma14112726
Źródła finansowania:
  • Program Power
Weryfikacja:
Politechnika Gdańska

wyświetlono 101 razy

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