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The influence of anchoring group position in ruthenium dye molecule on performance of dye-sensitized solar cells

Abstrakt

The effect of anchoring group position and, in consequence, the orientation of the ruthenium dye molecule on titania surface on the performance of dye-sensitized solar cells has been studied intensively. Three model ruthenium sensitizing dyes bearing carboxylic anchoring group in ortho, meta or para position were synthesized and well characterized by spectroscopic, electrochemical, photophysical and photochemical measurements. The results were confronted with the quantum-mechanical calculations and discussed. The para derivative has been found as the most effective sensitizer with the cells efficiency twice higher than the meta and four times higher than the ortho derivatives.

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Accepted albo Published Version
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Creative Commons: CC-BY-NC-ND otwiera się w nowej karcie

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Kategoria:
Publikacja w czasopiśmie
Typ:
artykuł w czasopiśmie wyróżnionym w JCR
Opublikowano w:
DYES AND PIGMENTS strony 335 - 346,
ISSN: 0143-7208
Język:
angielski
Rok wydania:
2018
Opis bibliograficzny:
Zals M., Gierczyk B., Bossi A., Mussini P., Klein M., Pankiewicz R., Makowska-Janusik M., Popenda Ł., Stampor W.: The influence of anchoring group position in ruthenium dye molecule on performance of dye-sensitized solar cells// DYES AND PIGMENTS. -, nr. 150 (2018), s.335-346
DOI:
Cyfrowy identyfikator dokumentu elektronicznego (otwiera się w nowej karcie) 10.1016/j.dyepig.2017.12.029
Weryfikacja:
Politechnika Gdańska

wyświetlono 177 razy

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