A magnetic imprinted polymer nano-adsorbent with embedded quantum dots and mesoporous carbon for the microextraction of triazine herbicides

Nurhasima Phirisi; Justyna Płotka-Wasylka; Opas Bunkoed

doi:10.1016/j.chroma.2024.464977

A magnetic imprinted polymer nano-adsorbent with embedded quantum dots and mesoporous carbon for the microextraction of triazine herbicides

Abstract

A magnetic molecularly imprinted polymer (MMIP) adsorbent incorporating amino-functionalized magnetite nanoparticles, nitrogen-doped graphene quantum dots and mesoporous carbon (MIP@MPC@NGQDs@ Fe3O4–NH2) was fabricated to extract triazine herbicides from fruit juice. The embedded magnetite nanoparticles simplified the isolation of the adsorbent from the sample solution. The N-GQDs and MPC enhanced adsorption by affinity binding with triazines. The MIP layer provided highly specific recognition sites for the selective adsorption of three target triazines. The extracted triazines were determined by high-performance liquid chromatography (HPLC) coupled with diode-array detection (DAD). The developed method exhibited linearity from 1.5 to 100.0 μg L 1 with a detection limit of 0.5 μg L 1. Recoveries from spiked fruit juice samples were in the range of 80.1– 108.4 %, with a relative standard deviation of less than 6.0 %. The developed MMIP adsorbent demonstrated good selectivity, high extraction efficiency, ease of fabrication and use, and good stability.

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Articles

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artykuły w czasopismach

Published in:

JOURNAL OF CHROMATOGRAPHY A no. 1726,
ISSN: 0021-9673

Language:

English

Publication year:

2024

Bibliographic description:

Phirisi N., Płotka-Wasylka J., Bunkoed O.: A magnetic imprinted polymer nano-adsorbent with embedded quantum dots and mesoporous carbon for the microextraction of triazine herbicides// JOURNAL OF CHROMATOGRAPHY A -Vol. 1726, (2024), s.464977-464987

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