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Determination of ionic conductivity in the Bi-Si-O and Pb-Si-O glasses

Abstract

Impedance spectroscopy measurements in various gas atmospheres were carried out in order to explain the doubts about the type of carriers and the mechanism of electrical conductivity in Bi-Si-O and Pb-Si-O glasses. In bismuth silicate glass, a typical ionic conductivity with oxygen ions as charge carriers was observed. The level of electrical conductivity of the glass at 400 °C was 5 × 10−8 S·cm−1 , with the activation energy of 1.3 eV and was independent of measuring atmosphere. In the case of lead silicate glasses, the conductivity changed with measuring atmosphere. Two types of charge carriers: oxygen ions and proton ions were postulated. Proton conductivity measured in wet argon at temperature 400 °C was estimated at the level of 4 × 10−8 S·cm−1 while the oxygen ions conductivity in such conditions was 78 × 10−8 S·cm−1 . We suggest that both types of charge carriers are transported along the same conduction paths using oxygen defects in the glass structure.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
MATERIALS SCIENCE-POLAND no. 35, pages 681 - 686,
ISSN: 0137-1339
Language:
English
Publication year:
2018
Bibliographic description:
Karczewski J., Miruszewski T., Bochentyn B., Kusz B.: Determination of ionic conductivity in the Bi-Si-O and Pb-Si-O glasses// MATERIALS SCIENCE-POLAND. -Vol. 35, nr. 4 (2018), s.681-686
DOI:
Digital Object Identifier (open in new tab) 10.1515/msp-2017-0102
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  1. KOHARA S., OHNO H., TAKATA M., USUKI T., MORITA H., SUZUYA K., AKOLA J., PUSZTAI L., Phys. Rev. B, 82 (2010), 134209. open in new tab
  2. WARREL C.A., HENSHALL T., J. Non-Cryst. Solids, 29 (1978), 283.
  3. KUSZ B., TRZEBIATOWKI K., BARCZYŃSKI R.J., Solid State Ionics, 159 (2003), 293. open in new tab
  4. LIU L., Z. Phys. B 90 (1993), 393. open in new tab
  5. WANG P.W., ZHANG L.P., J. Non-Cryst. Solids, 194 (1996), 129. open in new tab
  6. WITKOWSKA A., RYBICKI J., DI CICCO A., J. Non- Cryst. Solids, 351 (2005), 380. open in new tab
  7. KUSZ B., Optica Applicata 33 (2003), 141.
  8. GACKOWSKA J., GAZDA M., TRZEBIATOWSKI K., KUSZ B., J. Non-Cryst. Solids, 354 (2008), 4319. open in new tab
  9. ŁĄCZKA M., STOCH L., GÓRECKI J., J. Alloys and Compounds, 186 (1992), 279. open in new tab
  10. STEPIEN R., PYSZ D., KUJAWA I., BUCZYNSKI R., Optical Materials, 35 (2013), 1587. open in new tab
  11. KUSZ B., TRZEBIATOWSKI K., GAZDA M., MU- RAWSKI L., J. Non-Cryst. Solids, 319 (2003), 137. open in new tab
  12. HUGHES K., ISARD J.O., MILNES G.C., Phys. Chem. Glasses, 9 (1968), 43.
  13. STRAUSS S.W., MOORE D.G., HARRISON W.N., RICHARDS L.E., J. Res. Nat. Bur. Stand., 56 (1956), 135. open in new tab
  14. MENDIRATTA S.K., Phys. Stat. Sol.(A), 93 (1986), 293. open in new tab
  15. EL-BAYOUMI O.H., MACCRONE R.K., J. American Ceramic Society, 59 (1976), 386. open in new tab
  16. MILNES G.C., ISARD J.O., Phys. Chem. Glasses, 3 (1962), 157.
  17. ABE Y., HOSONS H., HIKICHI Y., J. Materials Science Letters, 9 (1990), 1443.
  18. PAVLOVA G.A., Izvest. Vysshykh Ucheb. Zavedenii Khim. i Khina. Teknol, 5 (1958), 82. open in new tab
  19. BOCHENTYN B., WARYCH A., SZREDER N., MIELEWCZYK-GRYŃ A., KARCZEWSKI J., PRZEŚNIAK-WELENC M., GAZDA M., KUSZ B., J. Non-Cryst. Solids, 439 (2016), 51. open in new tab
  20. BOCHENTYN B., KARCZEWSKI J., MIRUSZEWSKI T., KUSZ B., J. Alloys and Compounds, 646 (2015), 1124. open in new tab
  21. KUSZ B., MIRUSZEWSKI T., BOCHENTYN B., ŁAPIŃSKI M., KARCZEWSKI J., J. Electron. Mater., 45 (2016), 1085. open in new tab
  22. BOCHENTYN B., KARCZEWSKI J., MIRUSZEWSKI T., KUSZ B., Mat. Chem. Phys., 177 (2016), 353. open in new tab
  23. BOCHENTYN B., KARCZEWSKI J., MIRUSZEWSKI T., KUSZ B., Mater. Res. Bull., 76 (2016), 195. open in new tab
  24. ABE Y., TAKAHASI M., Chem. Phys. Lett., 411 (2005), 302.
  25. ABE Y., HOSONO H., OHTA Y., Phys. Rev. B, 38 (1988), 10166.
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