One-step formation of n-alkenyl-malonamides and n-alkenyl-thiomalonamides from carbamoyl meldrum's acids. - Publication - Bridge of Knowledge

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One-step formation of n-alkenyl-malonamides and n-alkenyl-thiomalonamides from carbamoyl meldrum's acids.

Abstract

A one-pot synthesis for the preparation of N-alkenyl-malonamides and N-alkenyl-thiomalonamides was developed. 5-[Hydroxy/mercapto(aryl/alkylamino)methylene]-2,2-dimethyl-1,3-dioxane-4,6-dione act as a source of ketenes that react with the tautomeric form of alkyl-(2-phenyl-propylidene)-amines. A possible [2+2] or [4+2] cycloaddition product of ketene to imines was not observed.

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Keywords

Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
SYNTHETIC COMMUNICATIONS no. 43, pages 1362 - 1367,
ISSN: 0039-7911
Language:
English
Publication year:
2013
Bibliographic description:
Punda P., Makowiec S.: One-step formation of n-alkenyl-malonamides and n-alkenyl-thiomalonamides from carbamoyl meldrum's acids.// SYNTHETIC COMMUNICATIONS. -Vol. 43, iss. 10 (2013), s.1362-1367
DOI:
Digital Object Identifier (open in new tab) 10.1080/00397911.2011.634082
Sources of funding:
  • Free publication
Verified by:
Gdańsk University of Technology

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