Abstract
This brief review is focussed on the recent progress in studies of the heterogeneous electrochemical behaviour of various boron-doped materials extending from zero-dimensional particles through polycrystalline or nanostructured three-dimensional surfaces. A boron-doped diamond reveals large heterogeneities induced by numerous factors, inter alia multi-faceted crystallinity, inhomogeneous boron concentration, sp2/sp3-carbon ratio, surface terminations and grain size distribution. We also present single nanodiamond particles and a nanostructured diamond, which are fabricated by either a top-down or a bottom-up procedure. Nanoarchitectured surfaces allow high areas and large aspect ratios to be achieved, exhibiting highly heterogeneous charge-transfer performance for catalytic, sensing and energy applications. We have anticipated multi-factor-originated heterogeneities of various boron-doped diamond surfaces displaying the essential fabrication and diagnostic methodologies and critically reviewing their benefits and drawbacks.
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.coelec.2021.100876
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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Current Opinion in Electrochemistry
no. 31,
ISSN: 2451-9103 - Language:
- English
- Publication year:
- 2022
- Bibliographic description:
- Bogdanowicz S., Ryl J.: Structural and electrochemical heterogeneities of boron-doped diamond surfaces// Current Opinion in Electrochemistry -, (2021), s.100876-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.coelec.2021.100876
- Sources of funding:
- Verified by:
- Gdańsk University of Technology
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