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Synthesis of malonylenamides and thiomalonylenamides

Abstract

5-[Hydroksyl(aryl(amino))methylene]-2,2-dimethyl-1,3-dioxane-4,6-dione is convenient source of ketenes which can be trapped with various nucleophiles like alcohols, thiols and amines. In reaction between in situ generated ketene and enolizable imines we can easily obtain corresponding malonylenamides. This facile method can be used to obtain thiomalonylenamides using 5-[sulfhydrylo(alkyl(amino))methylene]-2,2-dimethyl-1,3-dioxane-4,6-dione as a source of ketenes.

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Category:
Conference activity
Type:
publikacja w wydawnictwie zbiorowym recenzowanym (także w materiałach konferencyjnych)
Title of issue:
14th International Symposium of Students and Young Mechanical Engineers :''Advances in Chemical and Mechanical Engineering''. Vol. 2/2,Gdańsk, 5th-7th May 2011 strony 204 - 207
Language:
English
Publication year:
2011
Bibliographic description:
Punda P., Makowiec S.: Synthesis of malonylenamides and thiomalonylenamides// 14th International Symposium of Students and Young Mechanical Engineers :''Advances in Chemical and Mechanical Engineering''. Vol. 2/2,Gdańsk, 5th-7th May 2011/ ed. ed. C. Fijało. - Faculty Mechanical Engineering, Chemical Faculty Gdansk University of Technology. Gdańsk: , 2011, s.204-207
Verified by:
Gdańsk University of Technology

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