Marcin Tadeusz Erdanowski - Publications - Bridge of Knowledge

Marcin Tadeusz Erdanowski

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Year 2023

Reactive imines: Addition of 2-aminopyrimidine to the imine bond and isolation of the aminal from the equilibrium mixture aminal/imine
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- JOURNAL OF MOLECULAR STRUCTURE - Year 2023
The reaction between o-vanillin and 2-aminopyrimidine leads to the formation of a single crystalline product: aminal, 1, which results from the reaction of the initially formed imine with 2-aminopyrimidine. The reaction was followed by the NMR spectroscopy. VT NMR studies prove that in solution two major species are observed: aminal and imine and their ratio depends on the time or/and temperature with the imine content increasing...

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