A novel approach for processing CaAlSiON glass-ceramics by spark plasma sintering: Mechanical and electrical properties - Publication - Bridge of Knowledge

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A novel approach for processing CaAlSiON glass-ceramics by spark plasma sintering: Mechanical and electrical properties

Abstract

Lithium containing glassy materials can be used as solid electrolytes or electrode materials for lithium-ion batteries due to their high energy density. Conventional melt-quenched Ca11Al14Si16O49N10 glass powder containing 24 e/o N, doped with Li-ions (1, 3, and 6 wt. %) and sintered by spark plasma sintering technique (SPS) was studied. The benefits of using SPS to produce glass-ceramics are rapid heating rates compared to conventional consolidation techniques and tuning of properties, adjusting the temperature, holding time (closed to Tg temperature), heating rate (solidification), and pressure (densification) profile during the heat treatment using SPS. Pure glass and glass-ceramic were obtained under identical SPS conditions and compared with pristine oxynitride and soda-lime-silicate (float) glasses. XRD and SEM analysis confirmed that increasing the amount of Li increases the crystallinity in the glass matrix. Nano-indentation analysis showed a decreased hardness and reduced elastic modulus values with the addition of Li-ions. The direct current conductivity increases with the addition of Li due to the high mobility of Li-ions. However, the float glass sample doped with 6 wt.% of Li exhibits even higher values of D.C. conductivity, than the analogously doped Ca11Al14Si16O49N10 glass. The magnitude of activation energy (more than 1 eV) is typical for an ion hopping mechanism and the D.C. conduction mechanism is dominated by Li+ hopping.

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DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jeurceramsoc.2021.09.055
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Category:
Articles
Type:
artykuły w czasopismach
Published in:
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY no. 42, pages 96 - 104,
ISSN: 0955-2219
Language:
English
Publication year:
2022
Bibliographic description:
Ali S., Hakeem A. S., Eriksson M., Wójcik N.: A novel approach for processing CaAlSiON glass-ceramics by spark plasma sintering: Mechanical and electrical properties// JOURNAL OF THE EUROPEAN CERAMIC SOCIETY -Vol. 42,iss. 1 (2022), s.96-104
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jeurceramsoc.2021.09.055
Verified by:
Gdańsk University of Technology

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