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Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile
Abstract
Densities of some acetonitrile solutions of ionic liquids based on N-alkyl-N-methyl-morpholinium cations, N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide, N-methyl-N-octylmorpholinium bis(trifluoromethanesulfonyl)imide and N-decyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide were measured at T = (298.15− 318.15) K and at atmospheric pressure. From density data the apparent molar volumes and partial molar volumes of the ILs at infinite dilution as well as the limiting apparent molar expansibilities and the Hepler’s constant values have been evaluated. The results have been discussed in terms of the effect that alkyl chain length of the ILs and experimental temperature have on the ionic liquid−acetonitrile interactions occurring in the studied solutions.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
JOURNAL OF CHEMICAL AND ENGINEERING DATA
no. 59,
edition 3,
pages 718 - 725,
ISSN: 0021-9568 - Language:
- English
- Publication year:
- 2014
- Bibliographic description:
- Marcinkowski Ł., Olszewska T., Kloskowski A., Warmińska D.: Apparent Molar Volumes and Expansivities of Ionic Liquids Based on N-Alkyl-N-methylmorpholinium Cations in Acetonitrile// JOURNAL OF CHEMICAL AND ENGINEERING DATA. -Vol. 59, iss. 3 (2014), s.718-725
- DOI:
- Digital Object Identifier (open in new tab) 10.1021/je400790d
- Verified by:
- Gdańsk University of Technology
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